Abstract
We have analyzed experimental kinetic data for nitro compound consumption, for the formation of the corresponding amino product, and for the accumulation of intermediate products and by-products in the hydrogenation of chlorine-containing aromatic nitro compounds. The reaction has been carried out under static conditions over a platinum catalyst on a porous support in the presence of pyridine. The effect of the admixture on different hydrogenation steps of a chlorine-containing aromatic nitro compound has been quantitatively interpreted.
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Original Russian Text © V.G. Dorokhov, V.I. Savchenko, 2014, published in Kinetika i Kataliz, 2014, Vol. 55, No. 4, pp. 467–477.
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Dorokhov, V.G., Savchenko, V.I. Kinetics of the liquid-phase catalytic hydrogenation of chlorine-containing aromatic nitro compounds in the presence of pyridine. Kinet Catal 55, 446–455 (2014). https://doi.org/10.1134/S0023158414040028
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DOI: https://doi.org/10.1134/S0023158414040028