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Ethylene oxidation under conditions of the oxidative coupling of methane

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Abstract

Ethylene conversion under conditions of the oxidative coupling of methane has been investigated. In an empty reactor above 740°C, ethylene oxidation occurs at a higher rate and its main product is carbon monoxide. Filling the reactor with an inert material (quartz) or a NaWMn/SiO2 catalyst leads to a marked decrease in the ethylene conversion rate. Addition of methane to the reaction mixture dramatically slows down ethylene conversion rate and increases the C3 hydrocarbon content of the reaction products. The kinetics of ethylene oxidation in the presence of methane over the NaWMn/SiO2 catalyst is reported.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    V. I. Lomonosov, T. R. Usmanov, M. Yu. Sinev & V. Yu. Bychkov

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  1. V. I. Lomonosov
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  2. T. R. Usmanov
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  3. M. Yu. Sinev
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  4. V. Yu. Bychkov
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Correspondence to V. I. Lomonosov.

Additional information

Original Russian Text © V.I. Lomonosov, T.R. Usmanov, M.Yu. Sinev, V.Yu. Bychkov, 2014, published in Kinetika i Kataliz, 2014, Vol. 55, No. 4, pp. 498–505.

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Lomonosov, V.I., Usmanov, T.R., Sinev, M.Y. et al. Ethylene oxidation under conditions of the oxidative coupling of methane. Kinet Catal 55, 474–480 (2014). https://doi.org/10.1134/S0023158414030070

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  • DOI: https://doi.org/10.1134/S0023158414030070

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