Skip to main content
SpringerLink
Log in

Increase in the apparent rate constant of the reaction of hydrogen sulfide with ozone upon the treatment of the reactor surface with reaction products

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The reaction of hydrogen sulfide with ozone at 343 K was studied in a flow reactor whose inner surface was coated with 32-L fluoroplastic both immediately after coating and after repeatedly treating with reaction products (sulfur compounds). In the latter case, the rate of hydrogen sulfide reaction with ozone increased by more than one order of magnitude.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Karol’, I.L., Rozanov, V.V., and Timofeev, Yu.M., Gazovye primesi v atmosfere (Gaseous Impurities in the Atmosphere), Leningrad: Gidrometeoizdat, 1983.

    Google Scholar 

  2. Jaesshke, W., Slaude, H., Herrmann, J., and Vogler, D., Staub-Reinhalt Luft, 1979, vol. 39, p. 174.

    Google Scholar 

  3. Friend, J.P., Bandy, A.R., Maroulis, P.J., and Goldberg, A.B., Trans. Am. Geophys. Union, 1978, vol. 59, p. 1076.

    Google Scholar 

  4. Charison, R.J., Lovelock, J.E., Andreae, M.O., and Warren, S.G., Nature, 1987, vol. 326, p. 655.

    Article  Google Scholar 

  5. Platt, U. and Perner, D., J. Geophys. Res. C, 1980, vol. 85, p. 7453.

    Article  CAS  Google Scholar 

  6. Jaeschke, W. and Herrmann, J., Int. J. Environ. Anal. Chem., 1981, vol. 10.

  7. Gregor, I.K. and Martin, R.L., Aust. J. Chem., 1961, vol. 14, p. 462.

    CAS  Google Scholar 

  8. NIST Chemical Kinetics Database, Gaithersburg, Md.: National Inst. of Standards and Technology, 2000.

  9. Glavas, S. and Toby, S., J. Phys. Chem., 1975, vol. 79, p. 779.

    Article  CAS  Google Scholar 

  10. Hales, J.M., Wilkes, J.O., and York, J.L., Atmos. Environ., 1969, vol. 3, p. 657.

    Article  CAS  Google Scholar 

  11. Buben, S.N., Larin, I.K., Messineva, N.A., and Trofimova, E.M., Kinet. Katal., 1995, vol. 36, p. 812.

    Google Scholar 

  12. Larin, I.K., Messineva, N.A., Spasskii, A.I., Trofimova, E.M., and Turkin, L.E., Kinet. Katal., 2000, vol. 41, p. 496 [Kinet. Catal. (Engl. Transl.), vol. 41, p. 437].

    Google Scholar 

  13. Mitchell, A. and Zemanskii, M., Rezonansnoe izluchenie i vozbuzhdennye atomy (Resonance Emission and Excited Atoms), Moscow: ONTI NKTP, 1937.

    Google Scholar 

  14. Fizicheskaya khimiya bystrykh reaktsii (Physical Chemistry of Fast Reactions), Zaslonko, I.S., Ed., Moscow: Mir, 1976, p. 306.

    Google Scholar 

  15. Kump, L.R., Pavlov, A., and Arthur, M.A., Geology, 2005, vol. 33, p. 397.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Energy Problems of Chemical Physics, Moscow, 117829, Russia

    I. K. Larin, A. I. Spasskii, E. M. Trofimova & L. E. Turkin

Authors
  1. I. K. Larin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Spasskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. M. Trofimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. E. Turkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. M. Trofimova.

Additional information

Original Russian Text © I.K. Larin, A.I. Spasskii, E.M. Trofimova, L.E. Turkin, 2010, published in Kinetika i Kataliz, 2010, Vol. 51, No. 1, pp. 3–7.

About this article

Cite this article

Larin, I.K., Spasskii, A.I., Trofimova, E.M. et al. Increase in the apparent rate constant of the reaction of hydrogen sulfide with ozone upon the treatment of the reactor surface with reaction products. Kinet Catal 51, 1–5 (2010). https://doi.org/10.1134/S0023158410010015

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158410010015

Keywords

Search

Navigation