Skip to main content
SpringerLink
Log in

High catalytic activity and stability of palladium nanoparticles prepared by the laser electrodispersion method in chlorobenzene hydrodechlorination

  • III International Conference “Catalysis: Fundamentals and Applications”
  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

Palladium nanoparticles deposited on thermally oxidized silicon and on the carbon support Sibunit by the laser electrodispersion method are extremely active in the gas-phase hydrodechlorination of chlorobenzene at 100–200°C. High conversion of chlorobenzene (above 90%) has been achieved with catalysts with an unusually low metal content (from 10−4 to 10−3 wt %). The cyclohexane-to-benzene ratio in the reaction products depends on the process duration, palladium content, and support nature. According to X-ray photoelectron spectroscopy (XPS) data, palladium in the catalysts retains its metallic state over a long time under the reaction conditions. Possible causes of the high catalytic activity (105 mol (mol Pd)−1 h−1) of the palladium nanoparticles and their stability to chlorination are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kozhevin, V.M., Rostovshchikova, T.N., Yavsin, D.A., Zabelin, M.A., Smirnov, V.V., Gurevich, S.A., and Yassievich, I.N., Dokl. Akad. Nauk, 2002, vol. 387, no. 6, p. 785 [Dokl. Phys. Chem. (Engl. Transl.), vol. 387, nos. 4–6, p. 324].

    Google Scholar 

  2. Rostovshchikova, T.N., Yavsin, D.A., Smirnov, V.V., Kozhevin, V.M., and Gurevich, S.A., Kinet. Katal., 2003, vol. 44, no. 4, p. 607 [Kinet. Catal. (Engl. Transl.), vol. 44, no. 4, p. 555].

    Article  Google Scholar 

  3. Rostovshchikova, T.N., Smirnov, V.V., Gurevich, S.A., Kozhevin, V.M., Yavsin, D.A., Nevskaya, S.M., Nikolaev, S.A., and Lokteva, E.S., Catal. Today, 2005, vol. 105, p. 344.

    Article  CAS  Google Scholar 

  4. Nevskaya, S.M., Nikolaev, S.A., Noskov, Yu.T., Rostovshchikova, T.N., Smirnov, V.V., Gurevich, S.A., Zabelin, M.A., Kozhevin, V.M., Tret’yakov, P.A., Yavsin, D.A., and Vasil’kov, A.Yu., Kinet. Katal., 2006, vol. 47, no. 4, p. 657 [Kinet. Catal. (Engl. Transl.), vol. 47, no. 4, p. 638].

    Article  Google Scholar 

  5. Rostovshchikova, T.N., Smirnov, V.V., Kozhevin, V.M., Yavsin, D.A., Zabelin, M.A., Yassievich, I.N., and Gurevich, S.A., Appl. Catal., A, 2005, vol. 296, p. 70.

    Article  CAS  Google Scholar 

  6. Rostovshchikova, T.N., Smirnova, V.V., Kozhevin, V.M., Yavsin, D.A., and Gurevich, S.A., Ross. Nanotekhnol., 2007, vol. 2, nos. 1–2, p. 47.

    Google Scholar 

  7. Alonso, F., Beletskaya, I.P., and Yus, M., Chem. Rev., 2002, vol. 102, p. 4009.

    Article  CAS  Google Scholar 

  8. Urbano, F.J. and Marinas, J.M., J. Mol. Catal. A: Chem., 2001, vol. 173, p. 329.

    Article  CAS  Google Scholar 

  9. Zanaveskin, L.N. and Aver’yanov, V.A., Usp. Khim., 1998, vol. 67, no. 8, p. 788.

    CAS  Google Scholar 

  10. Lunin, V.V. and Lokteva, E.S., Izv. Akad. Nauk, Ser. Khim., 1996, no. 7, p. 1609.

  11. Kozhevin, V.M., Yavsin, D.A., Kouznetsov, V.M., Busov, V.M., Mikushkin, V.M., Nikonov, S.Yu., Gurevich, S.A., and Kolobov, A., J. Vac. Sci. Technol., B, 2000, vol. 18, no. 3, p. 1402.

    Article  CAS  Google Scholar 

  12. Kozhevin, V.M., Yavsin, D.A., Smirnova, I.P., Kulagina, M.M., and Gurevich, S.A., Fiz. Tverd. Tela, 2003, vol. 40, no. 10, p. 1895.

    Google Scholar 

  13. Teschner, D., Vas, E., Havecker, M., Zafeiratos, S., Schnorch, P., Sauer, H., Knop-Gericke, A., Schlogl, R., Chamam, M., Wootsch, A., Canning, A.S., Gamman, J.J., Jackson, S.D., McGregor, J., and Gladden, L.F., J. Catal., 2006, vol. 242, no. 1, p. 26.

    Article  CAS  Google Scholar 

  14. Chary, K.V.R., Naresh, D., Vishwanathan, V., Sadakane, M., and Ueda, W., Catal. Commun., 2007, vol. 8, no. 3, p. 471.

    Article  CAS  Google Scholar 

  15. Kohiki, Sh., Appl. Surf. Sci., 1986, vol. 25, nos. 1–2, p. 81.

    Article  CAS  Google Scholar 

  16. Stakheev, A.Yu. and Sachtler, W.M.H., J. Chem. Soc., Faraday Trans., 1991, vol. 87, no. 22, p. 3703.

    Article  CAS  Google Scholar 

  17. Kachevskii, S.A., Golubina, E.V., Lokteva, E.S., and Lunin, V.V., Zh. Fiz. Khim., 2007, vol. 81, no. 6, p. 998 [Russ. J. Phys. Chem. A (Engl. Transl.), vol. 81, no. 6, p. 866].

    Google Scholar 

  18. Bukhtiyarov, V.I. and Slin’ko, M.G., Usp. Khim., 2001, vol. 70, p. 167.

    Google Scholar 

  19. Gurevich, S.A., Kozhevin, V.M., Yassievich, I.N., Yavsin, D.A., Rostovshchikova, T.N., and Smirnov, V., in Thin Films and Nanostructures: Physico-Chemical Phenomena in Thin Films and at Solid Surfaces, Trakhtenberg, L.I., Lin, S.H., and Ilegbusi, O.J., Eds., Amsterdam: Elsevier, 2007, vol. 34, p. 726.

    Google Scholar 

  20. Coq, B. and Figueras, F., Coord. Chem. Rev., 1998, vol. 178-180, p. 1753.

    Article  CAS  Google Scholar 

  21. Aramendia, M.A., Borau, V., Garcia, I.M., et al., J. Mol. Catal. A: Chem., 2002, vol. 184, p. 237.

    Article  CAS  Google Scholar 

  22. Trakhtenberg, L.I., Gerasimov, G.N., Potapov, V.K., Rostovshchikova, T.N., Smirnov, V.V., and Zufman, V.Yu., Vestn. Mosk. Univ., Ser. 2: Kim., 2001, vol. 42, no. 5, p. 325.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119992, Russia

    E. S. Lokteva, T. N. Rostovshchikova, S. A. Kachevskii, E. V. Golubina & V. V. Smirnov

  2. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. Yu. Stakheev & N. S. Telegina

  3. Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg, 194021, Russia

    S. A. Gurevich, V. M. Kozhevin & D. A. Yavsin

Authors
  1. E. S. Lokteva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. N. Rostovshchikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. A. Kachevskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. V. Golubina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Yu. Stakheev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. N. S. Telegina
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. S. A. Gurevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. V. M. Kozhevin
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. D. A. Yavsin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. N. Rostovshchikova.

Additional information

Original Russian Text © E.S. Lokteva, T.N. Rostovshchikova, S.A. Kachevskii, E.V. Golubina, V.V. Smirnov, A.Yu. Stakheev, N.S. Telegina, S.A. Gurevich, V.M. Kozhevin, D.A. Yavsin, 2008, published in Kinetika i Kataliz, 2008, Vol. 49, No. 5, pp. 784–792.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lokteva, E.S., Rostovshchikova, T.N., Kachevskii, S.A. et al. High catalytic activity and stability of palladium nanoparticles prepared by the laser electrodispersion method in chlorobenzene hydrodechlorination. Kinet Catal 49, 748–755 (2008). https://doi.org/10.1134/S0023158408050212

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158408050212

Keywords

Search

Navigation