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Acid-catalyzed reactions of thiocyanates with camphene

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Abstract

The reactions of thiocyanates with camphene catalyzed by the heteropoly acids H3PW12O40 and H4SiW12O40 were studied. The optimal reaction conditions were found, and the formation of N-substituted thiocarbamates in comparatively high yields was established. It was shown that the heteropoly acids exhibit a higher catalytic activity than sulfuric acid.

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Authors and Affiliations

  1. Nizhni Novgorod State Technical University, Nizhni Novgorod, 603600, Russia

    A. V. Arkhipova, K. V. Malkova, T. N. Sokolova & V. R. Kartashov

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  1. A. V. Arkhipova
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  2. K. V. Malkova
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  3. T. N. Sokolova
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  4. V. R. Kartashov
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Correspondence to A. V. Arkhipova.

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Original Russian Text © A.V. Arkhipova, K.V. Malkova, T.N. Sokolova, V.R. Kartashov, 2008, published in Kinetika i Kataliz, 2008, Vol. 49, No. 3, pp. 412–415.

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Arkhipova, A.V., Malkova, K.V., Sokolova, T.N. et al. Acid-catalyzed reactions of thiocyanates with camphene. Kinet Catal 49, 391–394 (2008). https://doi.org/10.1134/S0023158408030117

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  • DOI: https://doi.org/10.1134/S0023158408030117

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