Skip to main content
SpringerLink
Log in

SYNTHESIS AND CRYSTAL STRUCTURES OF IONIC CLUSTER COMPLEXES [Cu2(en)2(μ-CN)][{Cu(en)}3Re6Q8(CN)6]·en·H2O (Q = S, Se)

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Two new compounds of the composition [Cu2(en)2(μ-CN)][{Cu(en)}3Re6Q8(CN)6]·en·H2O (Q = S, Se) are synthesized under solvothermal conditions from a mixture of CuCN, ethylenediamine (en), and Cs2.67K1.33[Re6S8(CN)2(OH)4]·4H2O or Cs2.75K1.25[Re6Se8(CN)4(OH)2]·H2O respectively. As a result of the reaction, CN– ligands substitute for OH– ones and fac-isomeric [{Cu(en)}3Re6Q8(CN)6]– anions are formed whose negative charge is compensated by the [Cu2(en)2(μ-CN)]+ complex cation. The compounds obtained are isostructural and they are characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

REFERENCES

  1. V. E. Fedorov, N. G. Naumov, Y. V. Mironov, A. V. Virovets, S. B. Artemkina, K. A. Brylev, S. S. Yarovoi, O. A. Efremova, and U. H. Peak. J. Struct. Chem., 2002, 43, 669. https://doi.org/10.1023/a:1022060806724

    Article  CAS  Google Scholar 

  2. V. E. Fedorov and N. G. Naumov. Struct. Bond., 2019, 180, 31. https://doi.org/10.1007/430_2019_33

    Article  Google Scholar 

  3. Y. V. Mironov, V. E. Fedorov, I. Ijjaali, and J. A. Ibers. Inorg. Chem., 2001, 40, 6320. https://doi.org/10.1021/ic010734s

    Article  CAS  PubMed  Google Scholar 

  4. K. A. Brylev, Y. V. Mironov, N. G. Naumov, V. E. Fedorov, and J. A. Ibers. Inorg. Chem., 2004, 43, 4833. https://doi.org/10.1021/ic040046j

    Article  CAS  PubMed  Google Scholar 

  5. K. A. Brylev, G. Pilet, N. G. Naumov, A. Perrin, and V. E. Fedorov. Eur. J. Inorg. Chem., 2005, 461. https://doi.org/10.1002/ejic.200400391

    Article  CAS  Google Scholar 

  6. N. G. Naumov, Y. V. Mironov, K. A. Brylev, and V. E. Fedorov. J. Struct. Chem., 2006, 47(4), 771. https://doi.org/10.1007/s10947-006-0369-6

    Article  CAS  Google Scholar 

  7. Y. V. Mironov, O. A. Efremova, and V. E. Fedorov. J. Struct. Chem., 2014, 55(5), 360. https://doi.org/10.1134/s0022476614020255

    Article  CAS  Google Scholar 

  8. Y. V. Mironov, S. S. Yarovoi, A. V. Ermolaev, and K. A. Brylev. Russ. J. Coord. Chem., 2012, 38, 264. https://doi.org/10.1134/s1070328412030074

    Article  CAS  Google Scholar 

  9. A. I. Smolentsev, A. V. Ermolaev, and Y. V. Mironov. J. Mol. Struct., 2012, 1014, 57. https://doi.org/10.1016/j.molstruc.2012.02.005

    Article  CAS  Google Scholar 

  10. A. V. Ermolaev, A. I. Smolentsev, and Y. V. Mironov. Russ. J. Coord. Chem., 2014, 40, 558. https://doi.org/10.1134/s1070328414080028

    Article  CAS  Google Scholar 

  11. A. V. Ermolaev, A. I. Smolentsev, and Y. V. Mironov. Polyhedron, 2015, 102, 417. https://doi.org/10.1016/j.poly.

    Article  CAS  Google Scholar 

  12. 10.024

  13. A. V. Ermolaev, A. I. Smolentsev, K. A. Brylev, N. Kitamura, and Y. V. Mironov. J. Mol. Struct., 2018, 1173, 627. https://doi.org/10.1016/j.molstruc.2018.07.028

    Article  CAS  Google Scholar 

  14. A. V. Ermolaev, A. I. Smolentsev, and Y. V. Mironov. Russ. J. Coord. Chem., 2021, 47, 473. https://doi.org/10.1134/S1070328421070022

    Article  CAS  Google Scholar 

  15. Y. V. Mironov, K. A. Brylev, A. I. Smolentsev, A. V. Ermolaev, N. Kitamura, and V. E. Fedorov. RSC Adv., 2014, 4, 60808. https://doi.org/10.1039/c4ra10697k

    Article  CAS  Google Scholar 

  16. N. G. Naumov, A. Y. Ledneva, S.-J. Kim, and V. E. Fedorov. J. Cluster Sci., 2009, 20, 225. https://doi.org/10.1007/s10876-009-0233-x

    Article  CAS  Google Scholar 

  17. APEX2 (Version 1.08), SAINT (Version 7.03), SADABS (Version 2.11). Madison, WI, USA: Bruker Advanced X-ray Solutions, 2004.

  18. G. M. Sheldrick. Acta Crystallogr., Sect. C, 2015, 71, 3. https://doi.org/10.1107/s2053229614024218

    Article  Google Scholar 

  19. DIAMOND (Version 3.2a). Bonn, Germany: Crystal Impact GbR, 2009.

  20. A. V. Ermolaev, A. I. Smolentsev, and Y. V. Mironov. J. Struct. Chem., 2011, 52(5), 1124. https://doi.org/10.1134/s0022476611060151

    Article  CAS  Google Scholar 

  21. A. V. Ermolaev, A. I. Smolentsev, and Y. V. Mironov. Russ. J. Coord. Chem., 2016, 42, 730. https://doi.org/10.1134/s1070328416110026

    Article  CAS  Google Scholar 

  22. K. Nakamoto. Infrared and Raman Spectra of Inorganic and Coordination Compounds. John Wiley & Sons, Inc., 2008, 1.

  23. G. Indramahalakshmi, A. Thamaraichelvan, R. Gandhidasan, S. Athimoolam, and S. Natarajan. Acta Crystallogr., Sect. E, 2007, 63, 2160. https://doi.org/10.1107/s1600536807032175

    Article  CAS  Google Scholar 

  24. A. Slougui, Y. V. Mironov, A. Perrin, and V. E. Fedorov. Croat. Chem. Acta, 1995, 68, 885.

  25. N. G. Naumov, A. V. Virovets, N. V. Podberezskaya, and V. E. Fedorov. J. Struct. Chem., 1997, 38(5), 857. https://doi.org/10.1007/bf02763902

    Article  CAS  Google Scholar 

Download references

Funding

The work was supported by the State Assignment of the Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences for basic research (CITIS No. 121031700321-3).

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Ermolaev, A. I. Smolentsev & Yu. V. Mironov

Authors
  1. A. V. Ermolaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Smolentsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. V. Mironov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Ermolaev.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 1, pp. 36-41.https://doi.org/10.26902/JSC_id85840

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ermolaev, A.V., Smolentsev, A.I. & Mironov, Y.V. SYNTHESIS AND CRYSTAL STRUCTURES OF IONIC CLUSTER COMPLEXES [Cu2(en)2(μ-CN)][{Cu(en)}3Re6Q8(CN)6]·en·H2O (Q = S, Se). J Struct Chem 63, 75–80 (2022). https://doi.org/10.1134/S0022476622010085

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476622010085

Keywords

Search

Navigation