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Hydrothermal Synthesis and Study of Compounds Based on Copper(I) Cyanide and Octahedral Rhenium CyanoHydroxo Cluster Complexes

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Abstract

Two new compounds, Cs2[Cu2Re6S8(CN)6]⋅3H2O (I) and (H3O)2[Cu{Cu2(µ-CN)}Re6Se8(CN)6]·6.5H2O (II), were synthesized under hydrothermal conditions from a mixture of CuCN and Cs2.67K1.33[Re6S8(CN)2(OH)4]·4H2O or Cs2.75K1.25[Re6Se8(CN)4(OH)2]·H2O, respectively. The reaction involves replacement of OH– by CN– and the formation of interpenetrating anionic framework through –CN–Cu–CN– bridges. The framework cavities accommodate counterions and water molecules. The obtained compounds were characterized by single crystal X-ray diffraction (CIF files CSD nos. 2048821 (I), 2048822 (II)), IR spectroscopy, and elemental analysis.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Ermolaev, A. I. Smolentsev & Yu. V. Mironov

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  1. A. V. Ermolaev
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  2. A. I. Smolentsev
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  3. Yu. V. Mironov
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Correspondence to A. V. Ermolaev.

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Translated by Z. Svitanko

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Ermolaev, A.V., Smolentsev, A.I. & Mironov, Y.V. Hydrothermal Synthesis and Study of Compounds Based on Copper(I) Cyanide and Octahedral Rhenium CyanoHydroxo Cluster Complexes. Russ J Coord Chem 47, 473–479 (2021). https://doi.org/10.1134/S1070328421070022

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  • DOI: https://doi.org/10.1134/S1070328421070022

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