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Structure of the {[Cu2Ge(μ-Cit)2(μ-INH)2]·4H2O} n Coordination Polymer Where H4Cit is Citric Acid, INH is Isonicotinic Acid Hydrazide

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Abstract

The {[Cu2Ge(μ-Cit)2(μ-INH)2]·4H2O} n (I) complex, where H4Cit is citric acid, INH is isonicotinic acid hydrazide, is synthesized for the first time and characterized by a set of physical and chemical analysis techniques. According to X-ray crystallography, I is a three-dimensional heteronuclear Cu–Ge coordination polymer with a completely deprotonated form Cit4– of citric acid. Both ligands are bridging and the framework structure of the complex is formed.

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Correspondence to E. E. Martsinko.

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Original Russian Text © 2018 I. I. Seifullina, E. E. Martsinko, E. A. Chebanenko, V. V. D’yakonenko, S. V. Shishkina, O. V. Pirozhok.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 158–163, January–February, 2018.

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Seifullina, I.I., Martsinko, E.E., Chebanenko, E.A. et al. Structure of the {[Cu2Ge(μ-Cit)2(μ-INH)2]·4H2O} n Coordination Polymer Where H4Cit is Citric Acid, INH is Isonicotinic Acid Hydrazide. J Struct Chem 59, 154–159 (2018). https://doi.org/10.1134/S0022476618010237

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