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CRYSTAL STRUCTURE OF [Cu(NH3)2]2[{Cu(NH3)}2{Cu(NH3)(OH)}Re6Se8(CN)6]

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Abstract

Chain coordination polymer [Cu(NH3)2]2[{Cu(NH3)}2{Cu(NH3)(OH)}Re6Se8(CN)6] (1) is obtained by a reaction of Cs2.75K1.25[Re6Se8(CN)4(OH)2]·H2O with CuCN in the concentrated aqueous ammonia solution under hydrothermal conditions. The compound crystallizes in the hexagonal crystal system with the P63/m space group and unit cell parameters a = 9.9902(2) Å, b = 9.9902(2) Å, c = 19.4469(7) Å, γ = 120.00°, V = 1680.85(8) Å3, Z = 2, dcalc= 4.661 g/cm3. The crystal structure is composed of anionic polymer chains [{Cu(NH3)}2{Cu(NH3)(OH)}Re6Se8(CN)6]2– and complex [Cu(NH3)2]+ cations located in cavities. The obtained compound is characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Ermolaev, A. I. Smolentsev & Yu. V. Mironov

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  1. A. V. Ermolaev
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  2. A. I. Smolentsev
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  3. Yu. V. Mironov
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Correspondence to Yu. V. Mironov.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 4, pp. 626-630.https://doi.org/10.26902/JSC_id71147

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Ermolaev, A.V., Smolentsev, A.I. & Mironov, Y.V. CRYSTAL STRUCTURE OF [Cu(NH3)2]2[{Cu(NH3)}2{Cu(NH3)(OH)}Re6Se8(CN)6]. J Struct Chem 62, 585–589 (2021). https://doi.org/10.1134/S0022476621040107

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