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Structure, synthesis, and thermal properties of trans-[Ru(NO)(NH3)4(SO4)]NO3·H2O

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Abstract

In treatment of trans-[Ru(NO)(NH3)4(OH)]Cl2 with concentrated sulfuric acid on heating trans-[Ru(NO)(NH3)4(SO4)](HSO4)·H2O (I) is obtained with a yield close to quantitative. In the interaction of the saturated solution of I with a saturated NaNO3 solution a trans-[Ru(NO)(NH3)4(SO4)]NO3·H2O (II) precipitate forms whose structure is determined by single crystal XRD: space group P212121, a = 6.8406(3) Å, b = 12.6581(5) Å, c = 13.3291(5) Å. A monodentately coordinated sulfate ion is in the trans-position to the nitroso group. Compound II is characterized by IR spectroscopy, powder XRD, and diffuse reflectance spectroscopy. The process of its thermolysis is studied; by differential scanning calorimetry the thermal effect of the dehydration reaction occurring on heating to 120°C (ΔH = 58.9 ± 1.5 kJ/mol) is estimated. The final product of the thermolysis of II is a mixture of Ru and RuO2.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. N. Makhinya, M. A. Il’in, I. A. Baidina, P. E. Plyusnin, N. I. Alferova & D. P. Pishchur

  2. Novosibirsk State University, Novosibirsk, Russia

    A. N. Makhinya, M. A. Il’in & P. E. Plyusnin

Authors
  1. A. N. Makhinya
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  2. M. A. Il’in
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  3. I. A. Baidina
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  4. P. E. Plyusnin
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  5. N. I. Alferova
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  6. D. P. Pishchur
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Correspondence to A. N. Makhinya.

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Original Russian Text © 2014 A. N. Makhinya, M. A. Il’in, I. A. Baidina, P. E. Plyusnin, N. I. Alferova, D. P. Pishchur.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 2, pp. 331–338, March–April, 2014.

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Makhinya, A.N., Il’in, M.A., Baidina, I.A. et al. Structure, synthesis, and thermal properties of trans-[Ru(NO)(NH3)4(SO4)]NO3·H2O. J Struct Chem 55, 311–318 (2014). https://doi.org/10.1134/S0022476614020188

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  • DOI: https://doi.org/10.1134/S0022476614020188

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