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Synthesis and crystal structure of [La(NO3)3(H2O)2(BiPy)]·1.5(BiPy)

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Abstract

The molecular and crystal structure of the [La(NO3)3(H2O)2(2.2′-BiPy)]·1.5(2.2′-BiPy) compound is determined. The metal coordination polyhedron in the La(III) complex is formed from 10 donor atoms of O8N2: 6 oxygen atoms belong to three chelate-coordinated NO −3 anions, 2 oxygen atoms belong to two water molecules, and 2 nitrogen atoms belong to a bidentate bipyridine molecule coordinated in the neutral form. The structure is based on the metal complexes linked together in chains through the O(W)-H...O hydrogen bonds, in which oxygen atoms of the coordinated NO −3 anions act as acceptors. It is a framework structure, further stabilized by a system of O(W)-H...N and C-H...N hydrogen bonds, in which nitrogen atoms of the uncoordinated bipyridine molecules act as proton acceptors.

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Authors and Affiliations

  1. Department of Inorganic and Physical Chemistry, and Electrochemistry, Polytechnical University of Bucharest, Bucharest, Romania

    L. Alexandrescu, O. Oprea & I. Jitaru

  2. Institute of Applied Physics, Academy of Sciences of Moldova, Chisinau, Moldova

    P. Bourosh

Authors
  1. L. Alexandrescu
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  2. P. Bourosh
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  3. O. Oprea
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  4. I. Jitaru
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Correspondence to P. Bourosh.

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Original Russian Text © 2014 S. L. Alexandrescu, P. Bourosh, O. Oprea, I. Jitaru.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 1, pp. 112–116, January–February, 2014.

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Alexandrescu, L., Bourosh, P., Oprea, O. et al. Synthesis and crystal structure of [La(NO3)3(H2O)2(BiPy)]·1.5(BiPy). J Struct Chem 55, 107–111 (2014). https://doi.org/10.1134/S002247661401017X

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  • DOI: https://doi.org/10.1134/S002247661401017X

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