It is shown that the process of light-induced resistive switching in films based on macroheterocyclic dyes correlates with the spatial localization of molecular orbitals (center or periphery in a coordination compound). External-illumination-induced spatial redistribution of charges can both promote the formation of a conducting state and prevent its formation. The transition from solution to a film in samples under study occurs without a significant distortion of the energy spectrum of molecules; for this reason, numerical methods of calculation of orbitals in isolated molecules can be applied to films. The prediction of the response of a system to an external action significantly simplifies the choice of materials with desired properties for practical applications.
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Funding
This work was supported by the Russian Foundation for Basic Research, project no. 20-32-70118. The characterization of films was supported by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools, project no. MK-1056.2020.3.
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Drozdov, K.A., Krylov, I.V., Vasilik, V.A. et al. Optimization of the Parameters of Light-Induced Resistive Switching in Phthalocyanine Films. Jetp Lett. 114, 674–680 (2021). https://doi.org/10.1134/S0021364021230065
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DOI: https://doi.org/10.1134/S0021364021230065