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Anomalous Ortho-to-Para Ratio of Nuclear Spin Isomers of H2O at Low Temperatures

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Abstract

A theoretical model proposed for nuclear spin isomers of H2O molecules located inside the C60 fullerene explains an anomalously high stability of ortho-H2O isomers detected in the experiments reported in [B. Meier et al., Nature Commun. 6, 8112 (2015)] at a temperature of T = 5 K.

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References

  1. L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics, Vol. 3: Quantum Mechanics: Non-Relativistic Theory (Nauka, Moscow, 1989, 4th ed.; Pergamon, New York, 1977, 3rd ed.).

    Google Scholar 

  2. T. Hama, A. Kouchi, and N. Watanabe, Science (Washington, DC, U. S.) 351, 65 (2016).

    Article  ADS  Google Scholar 

  3. K. Willacy, C. Alexander, M. Ali-Dib, C. Ceccarelli, S. B. Charnley, M. Doronin, Y. Ellinger, P. Gast, E. Gibb, S. N. Milam, O. Mousis, F. Pauzat, C. Tornow, E. S. Wirström, and E. Zicler, Space Sci. Rev. 197, 151 (2015).

    Article  ADS  Google Scholar 

  4. T. Hama, A. Kouchi, and N. Watanabe, Astrophys. J. Lett. 857, L13 (2018).

    Article  ADS  Google Scholar 

  5. D. C. Lis, T. G. Phillips, P. F. Goldsmith, et al., Astron. Astrophys. 521, L26 (2010).

    Article  ADS  Google Scholar 

  6. P. L. Chapovsky, Quantum Electron. 49, 473 (2019).

    Article  ADS  Google Scholar 

  7. C. Beduz, M. Carravettab, J. Y. Chenc, et al., Proc. Natl. Acad. Sci. U. S. A. 109, 12894 (2012).

    Article  ADS  Google Scholar 

  8. S. Mamone, M. Concistre, E. Carignani, B. Meier, A. Krachmalnicoff, O. G. Johannessen, X. Lei, Y. Li, M. Denning, M. Carravetta, K. Goh, A. J. Horsewill, R. J. Whitby, and M. H. Levitt, J. Chem. Phys. 140, 194306 (2014).

    Article  ADS  Google Scholar 

  9. B. Meier, S. Mamone, M. Concistre, et al., Nat. Commun. 6, 8112 (2015).

    Article  ADS  Google Scholar 

  10. I. E. Gordon, L. S. Rothman, C. Hill, et al., J. Quant. Spectrosc. Radiat. Transf. 203, 3 (2017).

    Article  ADS  Google Scholar 

  11. F. Matsushima, H. Nagase, T. Nakauchi, H. Odashima, and K. Takagi, J. Mol. Spectrosc. 193, 217 (1999).

    Article  ADS  Google Scholar 

  12. J. Tennyson, N. F. Zobov, R. Williamson, O. L. Polyansky, and P. F. Bernath, J. Phys. Chem. Ref. Data 30, 735 (2001).

    ADS  Google Scholar 

  13. R. F. Curl, Jr., J. V. V. Kasper, and K. S. Pitzer, J. Chem. Phys. 46, 3220 (1967).

    Article  ADS  Google Scholar 

  14. P. L. Chapovsky, Phys. Rev. A 43, 3624 (1991).

    Article  ADS  Google Scholar 

  15. P. L. Chapovsky and L. J. F. Hermans, Ann. Rev. Phys. Chem. 50, 315 (1999).

    Article  ADS  Google Scholar 

  16. Z. Sun, K. Takagi, and F. Matsushima, Science (Washington, DC, U. S.) 310, 1938 (2005).

    Article  ADS  Google Scholar 

  17. Z. D. Sun, M. Ge, and Y. Zheng, Nat. Commun. 6, 6877 (2015).

    Article  ADS  Google Scholar 

  18. B. Nagels, N. Calas, D. A. Roozemond, L. J. F. Hermans, and P. L. Chapovsky, Phys. Rev. Lett. 77, 4732 (1996).

    Article  ADS  Google Scholar 

  19. P. Cacciani, J. Cosléou, F. Herlemont, M. Khelkhal, and J. Lecointre, Phys. Rev. A 69, 032704 (2004).

    Article  ADS  Google Scholar 

  20. S. G. Rautian and A. M. Shalagin, Kinetic Problems of Nonlinear Spectroscopy (Elsevier Sci., Amsterdam, 1991).

    Google Scholar 

  21. E. Ilisca and K. Bahloul, Phys. Rev. A 57, 4296 (1998).

    Article  ADS  Google Scholar 

  22. G. Cazzoli, C. Puzzarini, M. E. Harding, and J. Gauss, Chem. Phys. Lett. 473, 21 (2009).

    Article  ADS  Google Scholar 

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Acknowledgments

We are grateful to E.V. Podivilov and A.M. Shalagin for stimulating discussions.

Funding

This work was supported by the Russian Science Foundation (project no. 17-12-01418).

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Correspondence to P. L. Chapovsky.

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Russian Text © The Author(s), 2020, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2020, Vol. 111, No. 2, pp. 75–79.

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Chapovsky, P.L., Mamrashev, A.A. Anomalous Ortho-to-Para Ratio of Nuclear Spin Isomers of H2O at Low Temperatures. Jetp Lett. 111, 85–89 (2020). https://doi.org/10.1134/S002136402002006X

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  • DOI: https://doi.org/10.1134/S002136402002006X

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