Skip to main content
Log in

Ultrapure arsenic and its compounds for optical and semiconductor materials

  • Published:
Inorganic Materials Aims and scope

Abstract

The article contains a survey of methods of deep purification of elemental arsenic and its compounds used in technology of optical, optoelectronic, and semiconductor materials. Severe requirements on permissible impurity content (ppb level) and features of structure and properties of these substances make the process of their production in the state of high purity unescapably multistage. The physics and chemistry and factors determining efficiency of the developed processing routes and the attained purity level for the arsenic, its oxide, chloride, hydride, and sulfides are described in this paper.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Hollan, L., Hallais, J.P., and Brice, J.C., The preparation of gallium arsenide, in Current Topics in Materials Science, Kaldis, E., Ed., Amsterdam: North-Holland, 1980, vol. 5, chap. 1, p. 155.

    Google Scholar 

  2. Snopatin, G., Shiryaev, V., Plotnichenko, V., Dianov, E., and Churbanov, M., High-purity chalcogenide glasses for fiber optics, Inorg. Mater., 2009, vol. 45, no. 13, pp. 1439–1460.

    Article  CAS  Google Scholar 

  3. Rtskhiladze, V.G., Mysh’yak (Arsenic), Moscow: Metallurgiya, 1969.

    Google Scholar 

  4. Devyatykh, G.G. and Elliev, Yu.E., Vvedenie v teoriyu glubokoi ochistki veshchestv (Introduction to the Theory of Deep Purification of Substances), Moscow: Nauka, 1981.

    Google Scholar 

  5. Devyatykh, G.G., Karpov, Yu.A., and Osipova, L.I., Vystavka-kollektsiya veshchestv osoboi chistoty (Exhibition- Collection of High Purity Substances), Moscow: Nauka, 2003.

  6. Churbanov, M.F., Chemistry of high-purity substances, Neorg. Mater., 2009, vol. 45, no. 9, pp. 1029–1034.

    Article  Google Scholar 

  7. Churbanov, M.F., Relevant problems of chemistry of high-purity substances, Inorg. Mater., 2009, vol. 45, no. 9, pp. 955–960.

    Article  CAS  Google Scholar 

  8. Fedorov, V.A., Efremov, A.A., Zhukov, E.G., et al., Synthesis of high-purity arsenic from the products of lewisite detoxification, Ross. Khim. Zh., 1995, vol. 39, no. 4, pp. 46–57.

    CAS  Google Scholar 

  9. Fedorov, V.A., Potolokov, N.A., Nikolashin, V.N., et al., Physical chemistry and production technology of high purity arsenic and its compounds of lewisite detoxification, Ross. Khim. Zh., 1995, vol. 39, no. 4, pp. 56–66.

    Google Scholar 

  10. Turygin, V.V., Smirnov, M.K., Smetanin, A.V., Zhukov, E.G., Fedorov, V.A., and Tomilov, A.P., Electrochemical arsenic extraction from nonferrous metals industry waste, Inorg. Mater., 2008, vol. 44, no. 9, pp. 946–953.

    Article  CAS  Google Scholar 

  11. Fedorov, V.A., Pashinkin, A.S., Efremov, A.A., and Grinberg, E.E., Physical-chemical principles of high purity arsenic production from sulfide ores, Vysokochist. Veshchestva, 1991, no. 5, pp. 7–30.

    Google Scholar 

  12. Evstaf’ev, I.B. and Kholstov, V.I., The problem of destruction of chemical weapon, Ross. Khim. Zh., 1993, vol. 37, no. 3, p. 3.

    Google Scholar 

  13. Umarov, I.Ya., Kuznetsov, B.A., Krotovich, I.N., and Kholstov, V.I., The methods of destruction and utilization of lewisite and yperite reserves, Ross. Khim. Zh., 1993, vol. 37, no. 3, pp. 25–29.

    Google Scholar 

  14. Fedorov, V.A., Efremov, A.A., Grinberg, E.E., et al., Production of high purity arsenic and its compounds based on lewisite, Ross. Khim. Zh., 1994, vol. 38, no. 2, pp. 25–33.

    CAS  Google Scholar 

  15. Fedorov, V.A., Zhukov, E.G., Nikolashin, S.V., Potolokov, V.N., Serov, A.V., and Smetanin, A.V., Sublimation purification of crude arsenic recovered from nonferrous waste, Inorg. Mater., 2001, vol. 37, no. 10, pp. 1011–1016.

    Article  CAS  Google Scholar 

  16. Zhukov, E.G., Nikolashin, S.V., Babitsina, A.A., Polulyak, E.S., and Fedorov, V.A., Vacuum sublimation purification of technical arsenic, Vysokochist. Veshchestva, 1995, no. 5, pp. 49–54.

    Google Scholar 

  17. Shiryaev, V.S., Skripachev, I.V., Snopatin, G.E., Suchkov, A.I., Churbanov, M.F., and Pushkin, A.A., Heterophase admixtures in high purity arsenic, Vysokochist. Veshchestva, 1995, no. 3, pp. 114–123.

    Google Scholar 

  18. Churbanov, M.F., Shiryaev, V.S., Fedorov, V.A., Skripachev, I.V., and Lukin, D.V., Influence of evaporation rate on purification efficiency from submicron particles by vacuum sublimation of arsenic, Vysokochist. Veshchestva, 1995, no. 6, pp. 38–43.

    Google Scholar 

  19. Skripachev, I.V., Vinokurov, A.K., and Churbanov, M.F., Interaction of arsenic vapors with quartz glass, Vysokochist. Veshchestva, 1988, no. 1, pp. 221–222.

    Google Scholar 

  20. Pashkov, V.M., Deep purification of arsenic by direct crystallization, Vysokochist. Veshchestva, 1988, no. 1, pp. 123–126.

    Google Scholar 

  21. Nisel’son, L.A., Yaroshevskii, A.G., and Kochurov, A.Z., Crystal-liquid and liquid-vapor balances in the arsenicadmixture systems, Vysokochist. Veshchestva, 1989, no. 2, pp. 76–78.

    Google Scholar 

  22. Nisel’son, L.A., Gasanov, A.A., and Yaroshevskii, A.G., Crystal/liquid and liquid/vapor balances in the arsenicadmixture systems. 2. Interphase distribution coefficients of selenium and tellurium admixtures, Vysokochist. Veshchestva, 1990, no. 2, pp. 68–71.

    Google Scholar 

  23. Nisel’son, L.A., Gasanov, A.A., and Yaroshevskii, A.G., Crystal-melt and melt-vapor balance in the arsenic-tellurium system, Vysokochist. Veshchestva, 1991, no. 6, pp. 97–104.

    Google Scholar 

  24. Nisel’son, L.A., Gasanov, A.A., and Yaroshevskii, A.G., Liquid-vapor equilibrium in the arsenic-selenium system, Vysokochist. Veshchestva, 1993, no. 6, pp. 56–61.

    Google Scholar 

  25. Nisel’son, L.A. and Gasanov, A.A., Influence of oxygen on interaction of elementary arsenic with quartz glass at the high temperatures, Vysokochist. Veshchestva, 1992, no. 1, pp. 86–92.

    Google Scholar 

  26. Yangzhou Crown New Material promotional material. http://yzrown.com.

  27. Demikhin, A.G. and Fedorov, V.A., Improvement of production technology of high-purity arsenic from arsenic trioxide, Mater. XIV konf. “Vysokochistye veshchestva i mateirlay. Poluchenie, analiz, primenenie,” Nizhnii Novgorod, 30 maya–2 iyunya 2011, Tezisy dokladov (Proc. XIV Conf. “High-Purity Substances and Materials: Synthesis, Analysis, and Implementation,” Nizhny Novgorod, May 30–June 2, 2011, Abstracts of Papers), Nizhny Novgorod, 2011.

    Google Scholar 

  28. Gabisiani, G.G., Fenina, M.Yu., Grinberg, E.E., Bessarabov, A.M., Omiadze, A.P., and Efremov, A.A., Kinetics of synthesis of ultra high-purity arsenic alkoxides, Vysokochist. Veshchestva, 1987, no. 4, pp. 88–91.

    Google Scholar 

  29. Grinberg, E.E., Omiadze, A.P., Gabisiani, G.G., Krasavin, V.P., and Efremov, A.A., Purification of ethers of arsenous acid and analysis of their physicalchemical properties, Vysokochist. Veshchestva, 1987, no. 2, pp. 83–90.

    Google Scholar 

  30. Fedorov, V.A., Efremov, A.A., Efremov, V.A., and Filippov, E.P., Poluchenie trekhkhloristogo mysh’yaka osoboi chistoty (Synthesis of Ultra High-Purity Arsenic Trichloride), Moscow: Tsentr. Nauchno-Issled. Inst. Elektronika, 1978.

    Google Scholar 

  31. Efremov, A.A., Fedorov, V.A., Fetisov, Yu.M., Yushina, E.A., and Efremov, V.A., Chemical forms of sulfur microadmixtures in chlorides of elements of III-V groups of Periodic table, Vysokochist. Veshchestva, 1993, no. 5, pp. 82–102.

    Google Scholar 

  32. Efremov, V.A., Fedorov, V.A., Nikolashin, S.V., Efremov, A.A., and Efremova, T.A., Hydrolysis of germanium tetrachloride and arsenic trichloride in small water concentrations, Vysokochist. Veshchestva, 1996, no. 5, pp. 78–88.

    Google Scholar 

  33. Efremov, V.A., Potolokov, V.N., Nikolashin, S.V., and Fedorov, V.A., Interaction of water with GeCl4,SnCl4,and AsCl3, Inorg. Mater., 2002, vol. 38, no. 8, pp. 837–846.

    Article  CAS  Google Scholar 

  34. Yushina, E.A., Fedorov, V.A., Efremov, A.A., Efremov, V.A., Kazanskii, L.N., Trokhin, V.E., Nikolashin, S.V., and Menshchikova, T.K., Liquid-vapor equilibrium in binary systems based on arsenic trichloride. IV. The systems formed by arsenic trichloride with some chloroalkanes, Vysokochist. Veshchestva, 1994, no. 5, pp. 75–78.

    Google Scholar 

  35. Yushina, E.A., Fedorov, V.A., Fetisov, Yu.M., and Efremov, A.A., Hydrodynamics and kinetics of rectification purification of arsenic trichloride, Vysokochist. Veshchestva, 1993, no. 4, pp. 90–97.

    Google Scholar 

  36. Zel’venskii, Ya.D., Titov, A.A., and Shalygin, V.A., Rektifikatsiya razbavlennykh rastvorov (Rectification of Diluted Solutions), Moscow: Nauka, 1972.

    Google Scholar 

  37. Egorov, E.N., Fedorov, V.A., and Tolmachev, A.M., Prospective implementation of adsorption deep purification of substances for microelectronics, Vysokochist. Veshchestva, 1988, no. 2, pp. 31–43.

    Google Scholar 

  38. Efremov, A.A. and Fedorov, V.A., Dynamics and efficiency of sorption purification of substances in microconcentrations, Vysokochist. Veshchestva, 1990, no. 2, pp. 72–83.

    Google Scholar 

  39. Borisov, S.A., Efremov, A.A., and Fedorov, V.A., Influence of the type of final curve of base materials on efficiency of adsorption purification. I. Description of final curve of direct frontal method, Vysokochist. Veshchestva, 1996, no. 2, pp. 45–47.

    Google Scholar 

  40. Borisov, S.A., Efremov, A.A., and Fedorov, V.A., Influence of the type of final curve of base materials on efficiency of adsorption purification. II. Efficiency analysis of purification, Vysokochist. Veshchestva, 1996, no. 2, pp. 64–67.

    Google Scholar 

  41. Yushina, E.A., Lapshina, E.V., Yasminov, A.A., Efremov, A.A., and Fedorov, V.A., Microfiltration purification of arsenic trichloride, Vysokochist. Veshchestva, 1995, no. 5, pp. 42–48.

    Google Scholar 

  42. Potolokov, V.N., Efremov, V.A., Zhukov, E.G., Pashinkin, A.S., Potolokov, N.A., and Fedorov, V.A., Preparation of high-purity arsenic via hydrogen reduction of arsenic trichloride, Inorg. Mater., 2003, vol. 39, no. 1, pp. 15–21.

    Article  CAS  Google Scholar 

  43. Smetanin, A.V., Smirnov, M.K., Turygin, V.V., Chernykh, I.N., Khudenko, A.V., Fedorov, V.A., and Tomilov, A.P., Electrochemical preparation of arsenic and its compounds, Inorg. Mater., 2003, vol. 39, no. 1, pp. 22–36.

    Article  CAS  Google Scholar 

  44. Devyatykh, G.G. and Zorin, A.D., Letuchie neorganicheskie gidridy osoboi chistoty (The Volatile High-Purity Inorganic Hydrides), Moscow: Nauka, 1974.

    Google Scholar 

  45. Efremov, A.A., Morozov, V.I., and Fedorov, V.A., Absorption-adsorption deep purification of volatile inorganic hydrides, Vysokochist. Veshchestva, 1991, no. 1, pp. 115–123.

    Google Scholar 

  46. Kotkov, A.P., Modern status and achievements in synthesis of high-purity volatile inorganic hydrides of Vgroup, Mater. XIV konf. “Vysokochistye veshchestva i mateirlay. Poluchenie, analiz, primenenie,” Nizhnii Novgorod, 30 maya–2 iyunya 2011, Tezisy dokladov (Proc. XIV Conf. “High-Purity Substances and Materials: Synthesis, Analysis, and Implementation,” Nizhny Novgorod, May 30–June 2, 2011, Abstracts of Papers), Nizhny Novgorod, 2011, pp. 152–153.

    Google Scholar 

  47. Polezhaev, D.M., Sukhanov, A.Yu., Kotkov, A.P., Ermolaev, S.V., and Pushkarev, G.V., Separation of mixture carbon dioxide–arsine by low-temperature rectification at the high pressure, in Mater. konf. “Vysokochistye veshchestva i mateirlay. Poluchenie, analiz, primenenie,” Nizhnii Novgorod, 26–29 maya 2011, Tezisy dokladov (Proc. Conf. “High-Purity Substances and Materials: Synthesis, Analysis, and Implementation,” Nizhny Novgorod, May 26–29, 2015, Abstracts of Papers), Nizhny Novgorod, 2015, p. 42.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. A. Fedorov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fedorov, V.A., Churbanov, M.F. Ultrapure arsenic and its compounds for optical and semiconductor materials. Inorg Mater 52, 1339–1357 (2016). https://doi.org/10.1134/S0020168516130021

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168516130021

Keywords

Navigation