Abstract
This paper examines the growth of aligned ZnO nanorod arrays through chemical deposition from solution and the vapor phase. The nanorod alignment is ensured primarily by a thin layer of seeds—zinc oxide nanoparticles produced by decomposing zinc acetate directly on the substrate and aligned with their c axes normal to the substrate surface. The acetate route was used to produce nanorod arrays 1 × 1 mm in dimensions on substrates with photoresist.
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Heo, Y.W., Norton, D.P., Tien, L.C., et al., ZnO Nanowire Growth and Devices, Mater. Sci. Eng., R, 2004, vol. 47, pp. 1–47.
Law, M., Greene, L., Johnson, J., et al., Nanowire Dye-Sensitized Solar Cells, Nat. Mater., 2005, vol. 4, pp. 455–459.
Wang, Z.-L., Piezoelectric Nanogenerators Based on Zinc Oxide Nanowire Arrays, Science, 2006, vol. 312, pp. 242–246.
Kim, H.S., Lugo, F., Pearton, S.J., and Norton, D.P., Phosphorus Doped ZnO Light Emitting Diodes Fabricated via Pulsed Laser Deposition, Appl. Phys. Lett., 2008, vol. 92, pp. 108–112.
Martinson, A.B.F. et al., ZnO Nanotube Based Dye-Sensitized Solar Cells, Phys. Chem. Chem. Phys., 2006, vol. 8, pp. 4655–4659.
Baranov, A.N. et al., Growth of ZnO Nanorods from a Salt Mixture, Nanotechnology, 2005, vol. 16, p. 1918.
Znaidia, L., Soler Illia, G.J.A.A., Benyahia, S., et al., Oriented ZnO Thin Films Synthesis by Sol-Gel Process for Laser Application, Thin Solid Films, 2003, vol. 428, pp. 257–262.
Shan, F.K. and Yu, Y.S., Substrate Effects of ZnO Thin Films Prepared by PLD Technique, J. Eur. Ceram. Soc., 2004, vol. 24, pp. 1869–1872.
Chang, P.C. et al., ZnO Nanowires Synthesized by Vapor Trapping CVD Method, Chem. Mater., 2004, vol. 16, p. 5133.
Liu, Z. et al., Growth of ZnO Nanorods by Aqueous Solution Method with Electrodeposited ZnO Seed Layers, Appl. Surf. Sci., 2009, vol. 255, p. 6415.
Greene, L.E. et al., General Route to Vertical ZnO Nanowire Arrays Using Textured ZnO Seeds, Nano Lett, 2005, vol. 5, pp. 1231–1236.
Spravochnik khimika (Chemist’s Handbook), Nikol’skii, B.P., Ed., Moscow: Khimizdat, 1952, vol. 2, pp. 254–255.
Red’kin, A.N. et al., Elemental Vapor-Phase Synthesis of Nanostructured Zinc Oxide, Inorg. Mater., 2009, vol. 45, no. 11, pp. 1246–1251.
Kotova, O. et al., Gas-Phase Synthesis of Lanthanide(III) Benzoates Ln(Bz)3 (Ln = La, Tb, Lu), Russ. J. Coord. Chem., 2007, vol. 33, no. 6, pp. 454–457.
Wei, M., Zhi, D., and MacManus-Driscoll, J.L., Self-Catalysed Growth of Zinc Oxide Nanowires, Nanotechnology, 2005, vol. 16, pp. 1364–1368.
Greenwood, N.N. and Earnshaw, A., Chemistry of the Elements, Oxford: Butterworth, 1997. Translated under the title Khimiya elementov, Moscow: BINOM, Laboratoriya Znanii, 2008, vol. 2, p. 536.
Baruah, S. and Dutta, J., Hydrothermal Growth of ZnO Nanostructures, Sci. Technol. Adv. Mater., 2009, vol. 10, pp. 1–13.
Guo, M., Diao, P., and Cai, S., Hydrothermal Growth of Perpendicularly Oriented ZnO Nanorod Array Film and Its Photoelectrochemical Properties, Appl. Surf. Sci., 2005, vol. 249, pp. 71–75.
Petrov, T.G., Treivus, E.B., Punin, Yu.O., and Kasatkin, A.P., Vyrashchivanie kristallov iz rastvorov (Crystal Growth from Solutions), Leningrad: Nedra, 1983, 2nd ed., p. 200.
Govender, K., Boyle, D.S., Kenway, P.B., and O’Brien, P., Understanding the Factors That Govern the Deposition and Morphology of Thin Films of ZnO from Aqueous Solution, J. Mater. Chem., 2004, vol. 14, pp. 25–75.
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Original Russian Text © T.V. Plakhova, M.V. Shestakov, A.N. Baranov, 2012, published in Neorganicheskie Materialy, 2012, Vol. 48, No. 5, pp. 549–556.
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Plakhova, T.V., Shestakov, M.V. & Baranov, A.N. Effect of textured seeds on the morphology and optical properties of solution- and vapor-grown ZnO nanorod arrays. Inorg Mater 48, 469–475 (2012). https://doi.org/10.1134/S0020168512050135
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DOI: https://doi.org/10.1134/S0020168512050135