Skip to main content
SpringerLink
Log in

Vaporization Thermodynamics of GeO2 by High-Temperature Mass Spectrometry

  • PHYSICAL CHEMISTRY
  • Published:
Doklady Physical Chemistry Aims and scope Submit manuscript

Abstract

Vaporization of GeO2 (tetragonal and hexagonal) have been studied by the Knudsen effusion method in combination with mass spectrometry in the temperature range 1250–1370 K. It has been demonstrated that the saturated vapor over GeO2 consists of GeO and O2 molecules. Partial pressures of the equilibrium vapor components and their temperature dependences have been determined. The standard enthalpy of the heterogeneous reaction GeO2(s) = GeO(g) + 1/2O2(g) and the standard enthalpy of formation of GeO2 (∆fH\(_{{298}}^{^\circ }\)(GeO(g)) = −41.7 ± 17.6 kJ mol–1) have been determined by the second- and third-law calculations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Murad, S.N.A., Baine, P.T., McNeill, D.W., Mitchell, S.J.N., Armstrong, B.M., Modreanu, M., Hughes, G., and Chellappan, R.K., Solid-State Electron., 2012, vol. 78, p. 136. https://doi.org/10.1016/j.sse.2012.05.048

    Article  CAS  Google Scholar 

  2. Choudhury, A., Dalal, A., Dwivedi, S.M.M.D., Ghosha, A., Halder, N., Das, S., and Mondal, A., Mater. Res. Bull., 2021, vol. 142, p. 111397. https://doi.org/10.1016/j.materresbull.2021.111397

    Article  CAS  Google Scholar 

  3. Micoulaut, M., Cormier, L., and Henderson, G.S., J. Phys.: Condens. Matter, 2006, vol. 18, no. 45, p. R753.https://doi.org/10.1088/0953-8984/18/45/R01

    Article  CAS  Google Scholar 

  4. Davydov, V.I., Zh. Neorg. Khim., 1957, vol. 2, p. 1460.

    CAS  Google Scholar 

  5. Shimazaki, E., Matsumoto, N., and Niwa, K., Bull. Chem. Soc. Jpn., 1957, vol. 30, p. 969. https://doi.org/10.1246/bcsj.30.969

    Article  CAS  Google Scholar 

  6. Sasamoto, T., Kobayashi, M., and Sata, T., Characterization of High Temperature Vapors and Gases, in: Proceedings of the 20th Materials Research Symposium Held at the National Bureau of Standards, September 18–22, 1978, Gaithersburg, Maryland, Hastie, J.W., Ed., Issued October 1979, vol. 1, p. 283.

  7. Sasamoto, T., Kobayashi, M., and Sata, T., Shitsuryo Bunseki, 1981, vol. 29, no. 3, p. 249. https://doi.org/10.5702/massspec.29.249

    Article  CAS  Google Scholar 

  8. Drowart, J., Degreve, F., Verhaegen, G., and Colin, R., J. Chem. Soc., Faraday Trans., 1965, vol. 61, p. 1072. https://doi.org/10.1039/TF9656101072

    Article  CAS  Google Scholar 

  9. Glushko, V.P., Gurvich, L.V., Bergman, G.A., Veits, I.V., Medvedev, V.A., Khachkuruzov, G.A., and Yungman, V.S., Termodinamicheskie svoistva individual’nykh veshchestv (Thermodynamic Properties of Individual Substanses), vol. 2, parts 1, 2, Moscow: Nauka, 1979.

  10. Baret, G., Madar, R., and Bernard, C., J. Electrochem. Soc., 1991, vol. 138, no. 9, p. 2830. https://doi.org/10.1149/1.2086066

    Article  CAS  Google Scholar 

  11. Stolyarova, V.L., Ambrok, A.G., Nikolaev, E.N., and Semenov, G.A., Fiz. Khim. Stekla, 1977, vol. 3, no. 6, p. 635.

    CAS  Google Scholar 

  12. Bielz, T., Soisuwan, S., Kaindl, R., Tessadri, R., Tobbens, D.M., Klotzer, B., and Penner, S., J. Phys. Chem. C, 2011, vol. 115, no. 19, p. 9706. https://doi.org/10.1021/jp202457b

    Article  CAS  Google Scholar 

  13. Kamitsos, E.I., Yiannopoulos, Y.D., Karakassides, M.A., Chryssikos, G.D., and Jain, H., J. Phys. Chem., 1996, vol. 100, no. 28, p. 11755. https://doi.org/10.1021/jp960434+

    Article  CAS  Google Scholar 

  14. Drowart, J., Chatillon, C., Hastie, J., and Bonnell, D., Pure Appl. Chem., 2005, vol. 77, no. 4, p. 683. https://doi.org/10.1351/pac200577040683

    Article  CAS  Google Scholar 

  15. Roki, F.Z., Chatillon, C., Ohnet, M.N., and Jacquemain, D., J. Chem. Thermodyn., 2008, vol. 40, no. 3, p. 401. https://doi.org/10.1016/j.jct.2007.09.013

    Article  CAS  Google Scholar 

  16. Miller, J.L., Jr., McCormick, G.R., and Ampian, S.G., J. Am. Ceram. Soc., 1967, vol. 50, no. 5, p. 268. https://doi.org/10.1111/j.1151-2916.1967.tb15102.x

    Article  CAS  Google Scholar 

  17. Sidorov, L.N., Korobov, M.V., Zhuravleva, L.V., Mass-spektral’nye termodinamicheskie issledovaniya (Mass Spectral Thermodynamic Stidies). Moscow: Izd. Mosk. Univ., 1985.

  18. Kessler, T., Brück, K., Baktash, C., Beene, J.R., Geppert, Ch., Havener, C.C., Krause, H.F., Liu, Y., Schultz, D.R., Stracener, D.W., Vane, C.R., and Wendt, K., J. Phys. B, 2007, vol. 40, p. 4413. https://doi.org/10.1088/0953-4075/40/23/002

    Article  CAS  Google Scholar 

  19. Evseev, A.M. and Voronin, G.F., Termodinamika i struktura zhidkikh metallicheskikh splavov (Thermodynamics and Structure of Liquid Metal Alloys), Moscow: Izd. Mosk. Univ., 1966.

  20. Grubbs, F.E. and Beck, G., Technometrics, 1972, vol. 14, no. 4, p. 847. https://doi.org/10.2307/1267134

    Article  Google Scholar 

Download references

ACKOWLEDGMENTS

Studies were carried out with the use of equipment of the Shared Facility Center for Physical Methods of Investigation at IGIC RAS.

Funding

The work was supported by the Russian Science Foundation (project no. 21-13-00086).

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. S. Smirnov, K. G. Smorchkov, N. A. Gribchenkova & A. S. Alikhanyan

Authors
  1. A. S. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. G. Smorchkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. A. Gribchenkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Alikhanyan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. S. Smirnov.

Ethics declarations

The authors declare no conflicts of interest.

Additional information

Translated by G. Kirakosyan

The work is presented in the virtual issue “Young Scientists of the Russian Academy of Sciences.”

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Smirnov, A.S., Smorchkov, K.G., Gribchenkova, N.A. et al. Vaporization Thermodynamics of GeO2 by High-Temperature Mass Spectrometry. Dokl Phys Chem 501, 119–125 (2021). https://doi.org/10.1134/S0012501621120010

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0012501621120010

Keywords:

Search

Navigation