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Structural and kinetic continuum in the butadiene polymerization with titanium catalysts

  • Physical Chemistry
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Abstract

The short-time polymerization of butadiene induced by heterogeneous titanium catalysts was studied for the first time. In the 0.1−0.3 s time interval, polymerization is characterized by a considerable decrease in the chain propagation rate constant and 1,4-stereospecificity of the catalysts. A structure kinetic continuum model was proposed in which the initiation step and the first propagation steps are kinetically continuous. The violation of this continuity changes the catalyst stereospecificity and creates conditions for chain transfer reactions.

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Authors and Affiliations

  1. Ufa Institute of Chemistry, Russian Academy of Sciences, Ufa, 450054, Russia

    V. Z. Mingaleev, I. A. Ionova, K. S. Chirko, G. R. Mingaleeva, D. R. Sagitov & A. G. Yaparova

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  1. V. Z. Mingaleev
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  2. I. A. Ionova
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  3. K. S. Chirko
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  4. G. R. Mingaleeva
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  5. D. R. Sagitov
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  6. A. G. Yaparova
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Correspondence to V. Z. Mingaleev.

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Mingaleev, V.Z., Ionova, I.A., Chirko, K.S. et al. Structural and kinetic continuum in the butadiene polymerization with titanium catalysts. Dokl Phys Chem 476, 177–180 (2017). https://doi.org/10.1134/S0012501617100037

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  • DOI: https://doi.org/10.1134/S0012501617100037

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