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Nanostructured ZnS with random close-packed structure: Synthesis, formation rate, and crystal structure study

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Abstract

The chemical precipitation of nanocrystalline ZnS from aqueous alkaline solutions containing zinc ethylenediamine complex salt Zn(En)2+ and thiocarbonic acid diamide N2H4CS was studied in the course of time in terms of formal chemical kinetics. The ZnS formation rate was found to depend on the concentration of precipitation agent (N2H4CS) and to decrease with increasing the ligand (ethylenediamine) concentration, whereas the pH dependence is less pronounced. The size of resulting ZnS nanoparticles does not exceed 5 nm, and their crystal structure was identified as a random close packed structure.

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Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russia

    A. S. Vorokh, N. S. Kozhevnikova & V. G. Bamburov

  2. Ural Federal University, ul. Mira 19, Yekaterinburg, 620002, Russia

    A. S. Vorokh, N. S. Kozhevnikova & A. A. Uritskaya

Authors
  1. A. S. Vorokh
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  2. N. S. Kozhevnikova
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  3. A. A. Uritskaya
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  4. V. G. Bamburov
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Corresponding authors

Correspondence to A. S. Vorokh or N. S. Kozhevnikova.

Additional information

Original Russian Text © A.S. Vorokh, N.S. Kozhevnikova, A.A. Uritskaya, V.G. Bamburov, 2016, published in Doklady Akademii Nauk, 2016, Vol. 470, No. 4, pp. 417–420.

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Vorokh, A.S., Kozhevnikova, N.S., Uritskaya, A.A. et al. Nanostructured ZnS with random close-packed structure: Synthesis, formation rate, and crystal structure study. Dokl Phys Chem 470, 141–144 (2016). https://doi.org/10.1134/S0012501616100031

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  • DOI: https://doi.org/10.1134/S0012501616100031

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