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Combustion of model compositions based on furazanotetrazine dioxide and dinitrodiazapentane. I. Binary systems

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Combustion, Explosion, and Shock Waves Aims and scope

Abstract

The combustion behavior of high-energy systems based on furazano[3,4-e]tetrazine-4,6-dioxide and 2,4-dinitro-2,4-diazapentane with metal and energetic additives (Al, AlH3 ammonium perchlorate, ammonium dinitramide, and HMX) has been studied. The burning rate, combustion stability, and characteristic combustion temperatures with pressure variation are estimated. It is found that there is a critical burning rate above which a deflagration-to-explosion transition occurs. The critical conditions depend on the formulation of the compositions.

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References

  1. Energetic Condensed Systems: Brief Encyclopedic Dictionary, Ed. by B. P. Zhukov (Yanus-K, Moscow, 2000) [in Russian].

    Google Scholar 

  2. V. I. Pepekin, “Trends in Research of Explosives,” Khim. Fiz. 29(12), 8–17 (2010).

    Google Scholar 

  3. M. B. Talawar, R. Sivabalan, S. N. zAsthana, and H. Singh, “Novel Ultra-High Energy Materials,” Fiz. Goreniya Vzryva 41(3), 29–45 (2005) [Combust., Expl., Shock Waves 41 (3), 264–277 (2005)].

    Google Scholar 

  4. V. P. Sinditskii, V. Yu. Egorshev, M. V. Berezin, V. V. Serushkin, Yu. M. Milekhin, S. A. Gusev, and A. A. Matveev, “Combustion Characteristics and Mechanism of the High-Energy Caged Nitramine Hexanitrohexaazaisowurtzitane,” Zh. Khim. Fiz. 22(7), 64–69 (2003).

    Google Scholar 

  5. V. P. Sinditskii, V. Yu. Egorshev, and M. V. Berezin, “Investigation of Combustion Energy-Cyclic Nitramines,” Zh. Khim. Fiz. 22(4), 53–60 (2003).

    Google Scholar 

  6. A. M. Churakov, S. L. Ioffe, and V. A. Tartakovsky, “Synthesis of [1,2,5]oxadiazolo[3,4-e][1,2,3.4]tetrazine 4.6-di-N-oxide, “Mendeleev Commun. 5(6), 227–228 (1995).

    Article  Google Scholar 

  7. V. P. Zelenov, A. A. Lobanova, N. I. Lyukshenko, S. V. Sysolyatin, and A. I. Kalashnikov, “Behavior of [1,2,5]oxadiazolo[3,4-e] [1,2,3,4] tetrazine-4,6-di-N-oxide in Various Environments,” Izv. Akad. Nauk, Ser. Khim., No. 7, 1358–1362 (2008).

    Google Scholar 

  8. V. G. Kiselev, N. P. Gritsan, V. E. Zarko, P. I. Kalmykov, and V. A. Shandakov, “Multilevel Quantum Chemical Calculation of the Enthalpy of Formation [1,2,5]oxadiazolo[3,4-e] [1,2,3,4] tetrazine-4,6-di-N-dioxide,” Fiz. Goreniya Vzryva 43(5), 77–81 (2007) [Combust., Expl., Shock Waves 43 (5), 562–566 (2007)].

    Google Scholar 

  9. V. I. Pepekin, Yu. N. Matushin, and T. V. Gubina, “Enthalpy of Formation and Explosive Properties of Furazanotetrazine Dioxide,” Khim. Fiz. 30(2), 42–45 (2011).

    Google Scholar 

  10. V. A. Teselkin, “Mechanical Sensitivity of Furazano-1,2,3,4-tetrazine-1,3-dioxide,” Fiz. Goreniya Vzryva 45(5), 140–142 (2009) [Combust., Expl., Shock Waves 45 (5), 632–633 (2009)].

    Google Scholar 

  11. P. I. Kalmykov, Yu. N. Burtsev, N. P. Kuznetsova, and V. V. Konstantinov, “Phase State and Structure Formation of Eutectic Alloys Based on DF-2,” in III All-Russian Conf. Energetic Condensed Systems, Chernogolovka, 2006, pp. 64–66.

  12. D. B. Lempert, G. N. Nechiporenko, and S. I. Soglasnova, “Dependence of the Specific Impulse of Rocket Propellant Compositions Containing Oxidizers Based on C, N, and O Atoms on the Enthalpy of Formation of the Elemental Composition of the Oxidizer,” Khim. Fiz. 23(5), 75–81 (2004).

    Google Scholar 

  13. V. P. Sinditskii, A. V. Burzhava, V. Yu. Yegorshev, A. B. Sheremetev, and V. P. Zelenov, “Combustion of Furazanotetrazine Dioxide,” Fiz. Goreniya Vzryva 49(1), 134–137 (2013) [Combust., Expl., Shock Waves 49 (1), 117–120 (2013)].

    Google Scholar 

  14. U. R. Nair, R. Sivabalan, G. M. Gore, M. Geetha, S. N. Asthana, and H. Singh, “Hexanitrohexaazaisowurtzitane (CL-20) and CL-20-based Formulations (Review),” Fiz. Goreniya Vzryva 41(2), 3–16 (2005) [Combust., Expl., Shock Waves 41 (2), 121–132 (2005)].

    Google Scholar 

  15. M. B. Talawar, R. Sivabalan, M. Anniyappan, M. B. Gore, S. N. Asthana, B. R. Gandhi, “Emerging Trends in Advanced High-Energy Materials,” Fiz. Goreniya Vzryva 43(1), 72–85 (2007) [Combust., Expl., Shock Waves 43 (1), 62–72 (2007)].

    Google Scholar 

  16. P. I. Kalmykov, A. A. Sidel’nikov, A. I. Ancharov, I. V. Koptyug, V. E. Zarko, and T. P. Ryabchikova, “Investigation of the Crystallization and Phase Structure of FTDO-DNP Binary Systems,” in Abstracts IV All-Russia. Conf. Energetic Condensed Systems, Chernogolovka, 2008, pp. 26–27.

  17. P. I. Kalmykov, V. E. Zarko, V. N. Simonenko, G. V. Romanenko, K. A. Sidorov, R. V. Rafikov, V. V. Erofeev, and A. V. Pozdnyakov, “Relationship between the Phase Structure and Combustion Behavior of FTDO-DNP Binary Systems,” in V All-Russian Conf. Energetic Condensed Systems, Chernogolovka, 2010, pp. 134–136.

  18. P. I. Kalmykov, V. E. Zarko, V. N. Simonenko, N. P. Vdovina, O. A. Troshina, and K. A. Sidorov, “Relationship between the Physicochemical Transformations of Furazanotetrazine Dioxide (FTDO) and the Combustion Behavior of Condensed Systems Based on It,” in XIV Symposium on Combustion and Explosion: Combustion and Kinetics, Chernogolovka, 2008, p. 79.

  19. P. I. Kalmykov, V. E. Zarko, A. A. Sidelnikov, I.V. Koptuyg, A. I. Ancharov, and K. A. Sidorov, “Crystal and Phase Structures of 5,6-(31,41-furazano)-1,2,3,4-tetrazine-1,3-dioxide-2.4-dinitro-2,4-diazapentane Binary Systems,” Zh. Prikl. Khim. 84(2), 252–259 (2011).

    Google Scholar 

  20. P. I. Kalmykov, Yu. N. Burtsev, N. P. Kuznetsova, I. A. Merzhanov, G. V. Romanenko, K. A. Sidorov, E. V. Artemova, V. V. Zakharov, and N. V. Chukanov, “Crystallization from the Melt and Phase Analysis of the [FTDO-DNP] Molecular Compound,” in VI All-Russian Conf. Energetic Condensed Systems, Chernogolovka, 2012, pp. 54–58.

  21. V. E. Zarko, A. A. Kvasov, A. I. Ancharov, K. E. Kuper, A. B. Kiskin, V. N. Simonenko, “X-ray Diffraction and Microscopy Studies of the Structure of Molecular Compound FTDO-DNAP,” in 40th Int. Conf. of ICT Energetic Materials. Characterization. Modeling and Validation, Karlsruhe, Germany, 2009, pp. 98-1–98-10.

  22. A. P. Denysiuk, Yu. G. Shepelev, S. V. Yudaev, and I. V. Kalashnikov, “Combustion of Systems Containing Linear Nitramines,” Fiz. Goreniya Vzryva 41(2), 98–107 (2005) [Combust., Expl., Shock Waves 41 (2), 206–214 (2005)].

    Google Scholar 

  23. A. G. Gorst, Gunpowder and Explosives (Gosizdatoboronprom, Moscow, 1957) [in Rusian].

    Google Scholar 

  24. K. K. Andreev and A. F. Belyaev, Theory of Explosives (Gosoborongiz, Moscow 1960) [in Rusian].

    Google Scholar 

  25. A. F. Belyaev, V. K. Bobolev, A. I. Korotkov, A. A. Sulimov, and S. V. Chuiko, Deflagration-to-Explosion Transition in Condensed Systems (Nauka, Moscow, 1973) [in Russian].

    Google Scholar 

  26. V. E. Zarko, V. N. Simonenko, P. I. Kalmykov, A. A. Kvasov, E. N. Chesnokov, and K. E. Kuper, “Laser Initiation and Crystallized Mixtures of Furazanotetrazine Dioxide Dinitrodiazapentane,” Fiz. Goreniya Vzryva 45(6), 131–134 (2009) [Combust., Expl., Shock Waves 45 (6), 752–755 (2009)].

    Google Scholar 

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Authors and Affiliations

  1. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Science, Novosibirsk, 630090, Russia

    V. N. Simonenko, A. B. Kiskin, O. G. Glotov & V. E. Zarko

  2. Altai Federal Research and Production Center, Biisk, 659322, Russia

    P. I. Kalmykov, K. A. Sidorov, B. V. Pevchenko & R. G. Nikitin

Authors
  1. V. N. Simonenko
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  2. P. I. Kalmykov
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  3. A. B. Kiskin
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  4. O. G. Glotov
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  5. V. E. Zarko
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  6. K. A. Sidorov
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  7. B. V. Pevchenko
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  8. R. G. Nikitin
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Corresponding author

Correspondence to V. N. Simonenko.

Additional information

Original Russian Text © V.N. Simonenko, P.I. Kalmykov, A.B. Kiskin, O.G. Glotov, V.E. Zarko, K.A. Sidorov, B.V. Pevchenko, R.G. Nikitin.

Published in Fizika Goreniya i Vzryva, Vol. 50, No. 3, pp. 68–77, May–June, 2014.

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Simonenko, V.N., Kalmykov, P.I., Kiskin, A.B. et al. Combustion of model compositions based on furazanotetrazine dioxide and dinitrodiazapentane. I. Binary systems. Combust Explos Shock Waves 50, 306–314 (2014). https://doi.org/10.1134/S0010508214030083

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  • DOI: https://doi.org/10.1134/S0010508214030083

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