Abstract
A high-pressure combustor and a metal/steam reactor are used to simulate the two-stage combustion of hydro-reactive propellants used for a water ramjet. Raw metal powders added to the propellants are the aluminum power, magnesium powder, 50/50 aluminum-magnesium alloy (AM), and ball-milled 50/50 aluminum-magnesium alloy (b-AM), which are characterized by using scanning electron microscopy (SEM), x-ray diffraction (XRD), and simultaneous thermogravimetric analysis (TGA). The efficiencies of the Al reaction in the raw metal in heated steam and in the propellants during the two-stage combustion are calculated. The results indicate that both Mg and Al in the alloys, whether b-AM or AM, can react completely in air when heated up to 950°C. The XRD patterns for the combustion products of the AM and b-AM alloys in heated steam contain magnesium oxide MgO, spinel Al2MgO4, and Al diffraction peaks. The Al reaction efficiencies of the AM and b-AM alloy powders in heated steam are much higher than that of the Al powders. The hydroxyl-terminated polybutadiene (HTPB)-ammonium perchlorate (AP)-(b-AM)-Mg and HTPB-AP-AM-Mg propellant systems exhibit good performance in terms of the Al reaction efficiency, which are better than that of the HTPB-AP-Al-Mg and HTPB-AP-Al systems.
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References
M. S. Zou, R. J. Yang, X. Y. Guo, et al., “The Preparation of Mg-Based Hydro Reactive Materials and Their Reactive Properties in Seawater,” Int. J. Hydrogen Energy, No. 36, 6478–6483 (2011).
W. M. Lee, “Aluminum Powder/Water Reaction Ignited by Electrical Pulsed Powder,” Research Report NSWC, AD-A269223 (1993).
J. D. Gerrard-Gough and A. B. Christman, History of the Naval Weapons Center (Printing Office, U.S. Govt., Washington, 1978).
L. Y. Huang, Z. Y. Xia, J. X. Hu, and Q. W. Zhu, Performance Study of a Water Ramjet Engine, Sci. China Ser. E, Technol. Sci. (in Netherlands), No. 54, 877–882 (2011).
D. H. Kiely, “Review of Underwater Thermal Propulsion,” AIAA-1994-2837 (1994).
A. Hahma, A. Gany, and K. Palovuori, “Combustion of Activated Aluminum,” Combust. Flame, No. 145, 464–480 (2006).
D. K. Kuehl, “Ignition and Combustion of Aluminum and Beryllium,” AIAA J. 3(12), 2239–2247 (1965).
V. P. Grachukho, E. S. Ozerov, and A. A. Yurinov, “Burning of Magnesium Particles in Water Vapor,” Fiz. Goreniya Vzryva 7(2), 232–236 (1971) [Combust. Expl., Shock Wave 7 (2), 195–198 (1971)].
E. S. Ozerov and A. A. Yurinov, “Combustion of Particles of Aluminum-Magnesium Alloys in Water Vapor,” Fiz. Goreniya Vzryva 13(6), 913–915 (1977) [Combust. Expl., Shock Wave 13 (6), 778–780 (1977)].
T. W. Megli, H. Krier, and R. Burton, “Shock Tube Ignition of Al/Mg Alloys in Water Vapor and Argon,” in Proc. of the 3rd World Conf. on Heat Transfer and Thermodynamics (Honolulu, HI, USA, 1993), pp. 1097–1105.
V. V. Gorbunov, “Combustion of Mixtures High-Calorific Metal Powders and Water,” Research Rep. NSWC, AD-2771789 (1973).
J. P. Foote and J. T. Lineberry, “Investigation of Aluminum Particle Combustion for Underwater Propulsion Applications,” AIAA-1996-3086 (1996).
S. L. Li and W. Zhang, “Thermal Decomposition Characteristics of Magnesium-Based Hydro Reactive Metal Fuel,” J. Propuls. Technol. (in Chinese) 30(6), 740–744 (2009).
G. A. Risha and Y. Huang, “Combustion of Aluminum Particles with Steam and Liquid Water,” AIAA-2006-1154, 2006.
S. L. Li, W. Zhang, X. Zhou, and D. L. Gao, “Study on Primary Combustion Wave Characteristics of Magnesium-Based Hydro Reactive Metal Fuel,” J. Solid Rocket Technol. (in Chinese) 32(2), 197–200 (2009).
T. F. Miller, J. L. Walter, and D. H. Kiely, “A Next-Generation AUV Energy System Based on Aluminum-Seawater Combustion,” in Symp. on Autonomous Underwater Vehicle Technology, San Antonio, TX, USA, 2002.
T. F. Miller and J. D. Herr, “Green Rocket Propulsion by Reaction of Al and Mg Powders and Water,” in 40th AIAA/ASME/SAE/ASEE Joint Propulsion Conf., AIAA-2004-4037 (2004).
A. V. Vasilev, V. V. Gorbunov, and A. A. Shidlovskii, “The Effect of Certain Additives on Critical Diameter and Combustion Rates of Mixtures of Aluminum with Gelled Water,” Research Rep. NSWC, AD-A000210 (1973).
K. Luo, J. J. Dang, and Y. C. Wang, “System Capability Estimating for a Metal-Water Reaction Fuel Ramjet System,” J. Propul. Technol. (in Chinese) 25(6), 495–498 (2004).
Z. P. Sun and F. R. Le, “Reaction Mechanism of Aluminum/Water,” Chem. Propell. and Polymer. Mater. (in Chinese) 4(2), 37–39 (2006).
Y. G. Zhang, A. M. Pang, W. Gang, and J. W. Xiao, “Research Status and Application Prospects of the Reaction between Metal Matrix Fuel and Water,” J. Solid Rocket Technol. (in Chinese) 29(1), 52–55 (2009).
A. L. Breiter, V. M. Mal’tsev, and E. I. Popov, “Modeles of Matel Ignition,” Fiz. Goreniya Vzryva 13(4), 558–570 (1977) [Combust., Expl., Shock Wave 13 (6), 475–484 (1977)].
L. Y. Huang, Z. X. Xia, and W. H. Zhang, “An Experimental Study on Rocket Propulsion by Reaction of Mg-Based Propellant and Water,” in Proc. of 60th Int. Astronaut. Congress (Daejeon, Korea, 2009).
K. Hori, O. G. Glotov, V. E. Zarko, and H. Habu, “Combustion of Mg and Al in Solid Propellants,” in Proc. of 23rd Int. Symp. of Space Technology and Science, Matsue, Japan, R: 02-a-08, 2002.
K. Hori., O. G. Glotov, V. E. Zarko, et al., “Study of the Combustion Residues for Mg/Al Solid Propellant,” in Energetic Materials: Synthesis, Production and Application: 33rd Int. Annu. Conf. of ICT (Karlsruhe, Germany, 2002), pp. 71-1–71-14.
P. C. Braithwaite, W. N. Christensen, and V. Daugherty, “Quench Bomb Investigation of Aluminum Oxide Formation from Solid Rocket Propellants. Pt I: Experimental Methodology,” in 25th JANNAF Combustion Meeting (Huntsville, AL), Chemical Propulsion Information Agency (Johns Hopkins Univ., Applied Physics Lab., CPIA-Pub-498-VI, Laurel, 1988), pp. 175–184.
Magnesium Technology: Metallurgy, Design Data, Applications, Ed. by H. E. Friedrich and B. L. Mordike (Springer, Berlin, Heidelberg, 2006), Vol. XXII.
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Original Russian Text © H.T. Huang, M.S. Zou, X.Y. Guo, R.J. Yang, Y.K. Li.
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Translated from Fizika Goreniya i Vzryva, Vol. 49, No. 5, pp. 39–46, September–October, 2013.
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Huang, H.T., Zou, M.S., Guo, X.Y. et al. Analysis of the aluminum reaction efficiency in a hydro-reactive fuel propellant used for a water ramjet. Combust Explos Shock Waves 49, 541–547 (2013). https://doi.org/10.1134/S0010508213050055
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DOI: https://doi.org/10.1134/S0010508213050055