Skip to main content
SpringerLink
Log in

Effect of the Compositions of Sample and Polymer Sorbents on the Extraction of Volatile Compounds by Solid-Phase Microextraction

  • Published:
Applied Biochemistry and Microbiology Aims and scope Submit manuscript

Abstract

A comparative study was performed by solid phase microextraction and capillary gas chromatography to establish the ability of four polymer sorbents of different compositions to extract and concentrate volatile organic compounds from the gas phase above an aqueous solution. All polymer sorbents sorbed nonpolar monoterpene hydrocarbons via a cooperative mechanism with almost equal and high efficiency. Sorbents based on polymethyl disiloxane and its mixture with divinylbenzene were more effective in extracting acetates and sesquiterpenes. As the concentration of these compounds in the gas phase increased, their binding by sorbents decreased. It was found that the determination of polar compounds depended on the presence of a solvent in the system. Compounds that are highly soluble in water (alcohols, ketones, etc.) had low coefficients of distribution between gas and water phases. Consequently, their sorption to any of the polymer sorbents was negligible. In the absence of the solvent, the degree of their extraction from the gas phase above the sample was high. It was shown that the actual composition of compounds in the initial mixture of essential oils could significantly differ from their composition in the gas phase. This method is convenient and informative for the purpose of studying the composition of volatile compounds in the gas phase that determine the flavor of the product.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Wardencky, W., Michulec, M., and Curylo, J., Int. J. Food Sci. Technol., 2004, vol. 39, pp. 703–717.

    Article  Google Scholar 

  2. Roberts, D.D., Polien, P., and Milo, C., J. Agric. Food Chem., 2000, vol. 48, no. 6, pp. 2430–2437.

    Article  CAS  PubMed  Google Scholar 

  3. Misharina, T.A., Prikl. Anal. Khim., 2010, vol. 1, no. 2, pp. 12–19.

    Google Scholar 

  4. Ouyang, G. and Vuckovic, D., Pawliszyn, J. Chem. Rev., 2011, vol. 111, no. 4, pp. 2784–2815.

    Article  CAS  Google Scholar 

  5. Arthur, C.L. and Pawliszyn, J., Anal. Chem., 1990, vol. 62, no. 7, pp. 1843–1852.

    Google Scholar 

  6. Ettre, L.S., in Headspace Analysis of Food and Flavours: Theory and Practice, Rouseff, R.L. and Cadwallader, K.R., Eds., New York: Academic Plenum Publ., 2001.

  7. Nongonierma, A., Cayot, P., Le Quere, J.L., Springett, M., and Voilley, A.J., Food Rew. Int., 2006, vol. 22, no. 1, pp. 51–94.

    Article  CAS  Google Scholar 

  8. Misharina, T.A., Terenina, M.B., and Krikunova, N.I., Appl. Biochem. Microbiol., 2017, vol. 53, pp. 5.

    Article  Google Scholar 

  9. Zaitsev, V.N. and Zui, M.F., Zh. Anal. Khim., 2014, vol. 69, no. 8, pp. 787–801.

    Google Scholar 

  10. Savel'eva, E.I., Gavrilova, O.P., and Gagkaeva, T.Yu., Zh. Anal. Khim., 2014, vol. 69, no. 7, pp. 675–682.

    Google Scholar 

  11. Bajer, T., Ligor, M., Ligor, T., and Buszewski, D., J. Separation Sci., 2016, vol. 39, no. 4, pp. 769–774.

    Article  CAS  Google Scholar 

  12. Souza, H.A.L. and Bragagnolo, N., J. Agric. Food Chem., 2014, vol. 62, no. 3, pp. 590–599.

    Article  CAS  PubMed  Google Scholar 

  13. Du, L., Wang Ch., Li, J., Xiao, D., Li, Ch., and Xu, Y., J. Agric. Food Chem., 2013, vol. 61, no. 2, pp. 561–568.

    Article  CAS  PubMed  Google Scholar 

  14. Golovnya, R.V. and Misharina, T.A., Usp. Khim., 1980, vol. 49, pp. 171–191.

    Article  CAS  Google Scholar 

  15. Terenina, M.B. and Misharina, T.A., Appl. Biochem. Microbiol., 2005, vol. 41, no. 4, pp. 407–412.

    Article  CAS  Google Scholar 

  16. Misharina, T.A., Terenina, M.B., Krikunova, N.I., and Kalinchenko, M.A., Appl. Biochem. Microbiol., 2006, vol. 42, no. 1, pp. 111–116.

    Article  CAS  Google Scholar 

  17. Misharina, T.A., Samusenko, A.L., and Kalinchenko, M.A., in From Polysaccharides to Granules, Simple and Mixture Gels, Yuryev, V.P. and Tomasik, P., Eds., New York: Nova Sci. Publ., 2004, pp. 245–257.

  18. Moradi, M., Kaykhali, M., Ghiasvand, A.R., Shadabi, S., and Salehinia, A., Phytochem. Anal., 2012, vol. 23, no. 2, pp. 379–386.

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 119334, Russia

    T. A. Misharina, M. B. Terenina & N. I. Krikunova

  2. Plekhanov Russian University of Economics, Moscow, 117997, Russia

    T. A. Misharina & I. A. Mihailov

Authors
  1. T. A. Misharina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. B. Terenina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. I. Krikunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. A. Mihailov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. A. Misharina.

Additional information

Original Russian Text © T.A. Misharina, M.B. Terenina, N.I. Krikunova, I.A. Mihailov, 2018, published in Prikladnaya Biokhimiya i Mikrobiologiya, 2018, Vol. 54, No. 1, pp. 89–98.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Misharina, T.A., Terenina, M.B., Krikunova, N.I. et al. Effect of the Compositions of Sample and Polymer Sorbents on the Extraction of Volatile Compounds by Solid-Phase Microextraction. Appl Biochem Microbiol 54, 89–97 (2018). https://doi.org/10.1134/S0003683818010052

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0003683818010052

Keywords

Search

Navigation