Abstract
In this work we investigated the stability of a-Si:H films under illumination and following recovery in darkness at different temperatures. The a-Si:H films were fabricated with 55 kHz PECVD and with conventional rf 13.56 MHz PECVD. We measured the steady-state photocurrent and the dark-current after switching off the light source as a function of time. We observed photocurrent degradation and the following recovery of the dark current. The kinetics of the photocurrent degradation as well as the dark-current recovery demonstrated stretched-exponential behavior. The results of these straightforward measurements in combination with computer simulation were used to determine the effect of light-induced degradation and thermal recovery on the density of states distribution in the band gap of a-Si:H. We have found that the photocurrent degradation and the corresponding increase in the total defect concentration have different kinetics. The different kinetics were also determined for the dark-current recovery and the corresponding decrease in the total defect concentration. The results point out that slow and fast types of defects in a-Si:H films control the kinetics of light-induced changes of the defect distribution in the band gap. A model is proposed that relates the origin of the fast and slow metastable defects with the distribution of Si-Si bond lengths.
Similar content being viewed by others
References
D. L. Staebler and C. Wronski, Appl. Phys. Lett. 31, 292 (1977).
P. Roca i Cabarrocas, J. Non-Cryst. Solids 164/166, 37 (1993).
B. G. Budaguan, A. A. Sherchenkov, D. A. Stryahilev, et al., in Proceedings of the Electrochemical Society Symposium, Paris, 1997.
R. Street and K. Winer, Phys. Rev. B 40, 6236 (1989).
A. S. Abramov, A. I. Kosarev, P. Roca i Cabarrocas, and A. J. Vinogradov, Mater. Res. Soc. Symp. Proc. 420, 659 (1996).
M. Zeman, J. A. Willimen, L. L. A. Vosteen, et al., Sol. Energy Mater. Sol. Cells 46, 81 (1997).
B. G. Budaguan and A. A. Aivazov, Mater. Res. Soc. Symp. Proc. (1998) (in press).
C. R. Wronski, in Semiconductors and Semimetals, Ed. by J.I. Pankove (Academic Press, New York, 1984), Vol. 21, Part C, p. 347.
J. Kakalios and W. B. Jackson, in Amorphous Silicon and Related Materials, Ed. by H. Fritzsche (World Scientific, Singapore, 1988).
R. Bube, L. E. Benatar, M. N. Grimbergen, and D. Redfield, J. Non-Cryst. Solids 169, 47 (1994).
Liyou Yang and Liang-Fan Chen, Mater. Res. Soc. Symp. Proc. 297, 619 (1993).
C. Godet and P. Roca i Cabarrocas, Mater. Res. Soc. Symp. Proc. 420, 647 (1996).
Qiming Li and R. Biswas, Appl. Phys. Lett. 68, 2261 (1996).
Author information
Authors and Affiliations
Additional information
From Fizika i Tekhnika Poluprovodnikov, Vol. 34, No. 6, 2000, pp. 742–747.
Original English Text Copyright © 2000 by Meytin, Zeman, Budaguan, Metselaar.
This article was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Meytin, M.N., Zeman, M., Budaguan, B.G. et al. Kinetics of light-induced degradation in a-Si:H films investigated by computer simulation. Semiconductors 34, 717–722 (2000). https://doi.org/10.1134/1.1188060
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1134/1.1188060