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Selective catalytic reduction of NO x over H-ZSM-5 under lean conditions using transient NH3 supply

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Abstract

The selective catalytic reduction (SCR) of NO x over zeolite H-ZSM-5 with ammonia was investigated using in situ FTIR spectroscopy and flow reactor measurements. The adsorption of ammonia and the reaction between NO x , O2 and either preadsorbed ammonia or transiently supplied ammonia were investigated for either NO or equimolar amounts of NO and NO2. With transient ammonia supply the total NO reduction increased and the selectivity to N2O formation decreased compared to continuous supply. The FTIR experiments revealed that NO x reacts with ammonia adsorbed on Brønsted acid sites as \({\rm NH}_{4}^{+}\) ions. These experiments further indicated that adsorbed -\({\rm NO}_{2}^{-}\) is formed during the SCR reaction over H-ZSM-5.

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References

  1. Sullivan J.A., Cunningham J., Morris M.A. and Keneavey K. (1995). Appl. Catal. B 7: 137–151

    Article  CAS  Google Scholar 

  2. Ramachandran B., Herman R.G., Choi S., Stenger H.G., Lyman C.E. and Sale J.W. (2000). Catal. Today 55: 281–290

    Article  CAS  Google Scholar 

  3. Kieger S., Delahay G. and Coq B. (2000). Appl. Catal. B 25: 1–9

    Article  CAS  Google Scholar 

  4. T. Seiyama, T. Arakawa, T. Matsuda, Y. Takita and N. Yamazoe J. Catal. 48 (1977) 1—7 etc.

  5. Kiovsky J.R., Koradia P.B. and Lim C.T. (1980). Ind. Eng. Chem. Prod. Res. Dev. 19: 218–225

    Article  CAS  Google Scholar 

  6. Komatsu T., Ueda T. and Yashima T. (1998). J. Chem. Soc.-Faraday Trans. 94: 949–953

    Article  CAS  Google Scholar 

  7. Stevenson S.A., Vartuli J.C. and Brooks C.F. (2000). J. Catal. 190: 228–239

    Article  CAS  Google Scholar 

  8. Brandin J.G.M., Andersson L.A.H. and Odenbrand C.U.I. (1989). Catal. Today 4: 187–203

    Article  CAS  Google Scholar 

  9. Koebel M., Madia G., Raimondi F. and Wokaun A. (2002). J. Catal. 209: 159–165

    Article  CAS  Google Scholar 

  10. Richter M., Eckelt R., Parlitz B. and Fricke R. (1998). Appl. Catal. B 15: 129–146

    Article  CAS  Google Scholar 

  11. Wallin M., Karlsson C.-J., Skoglundh M. and Palmqvist A. (2003). J. Catal. 218: 354–364

    Article  CAS  Google Scholar 

  12. Jansson J., Palmqvist A.E.C., Fridell E., Skoglundh M., Österlund L., Thormählen P. and Langer V. (2002). J. Catal. 211: 387–397

    CAS  Google Scholar 

  13. Jentys A., Warecka G. and Lercher J.A. (1989). J. Mol. Catal. 51: 309–327

    Article  CAS  Google Scholar 

  14. Sun Q., Gao Z.X., Wen B. and Sachtler W.M.H. (2002). Catal. Lett. 78: 1–5

    Article  CAS  Google Scholar 

  15. Teunissen E.H., Jansen A.P.J., van Santen R.A. and van Duijneveldt F.B. (1993). J. Phys. Chem. 97: 203–210

    Article  CAS  Google Scholar 

  16. Szostak R. (1989). Molecular Sieves. Van Nostrand Reinhold, New York

    Google Scholar 

  17. Jansen J.C., Vandergaag F.J. and Vanbekkum H. (1984). Zeolites 4: 369–372

    Article  CAS  Google Scholar 

  18. Fanning P.E. and Vannice M.A. (2002). J. Catal. 207: 166–182

    Article  CAS  Google Scholar 

  19. Eng J. and Bartholomew C.H. (1997). J. Catal. 171: 27–44

    Article  CAS  Google Scholar 

  20. Wakabayashi F., Kondo J.N., Domen K. and Hirose C. (1996). Catal. Lett. 38: 15–19

    Article  CAS  Google Scholar 

  21. Hadjiivanov K.I. (2000). Catal. Rev. -Sci. Eng. 42: 71–144

    Article  CAS  Google Scholar 

  22. Hadjiivanov K., Saussey J., Freysz J.L. and Lavalley J.C. (1998). Catal. Lett. 52: 103–108

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Competence Centre for Catalysis Chalmers University of Technlogy, SE-412 96, Göteborg, Sweden

    Mikaela Wallin, Carl-Johan Karlsson, Anders Palmqvist & Magnus Skoglundh

  2. Applied Surface Chemistry, Chalmers University of Technology, SE-412 96, Göteborg, Sweden

    Mikaela Wallin, Carl-Johan Karlsson, Anders Palmqvist & Magnus Skoglundh

  3. Volvo Technology Corporation, SE-412 88, Göteborg, Sweden

    Anders Palmqvist

Authors
  1. Mikaela Wallin
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  2. Carl-Johan Karlsson
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  3. Anders Palmqvist
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  4. Magnus Skoglundh
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Correspondence to Mikaela Wallin.

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Wallin, M., Karlsson, CJ., Palmqvist, A. et al. Selective catalytic reduction of NO x over H-ZSM-5 under lean conditions using transient NH3 supply. Topics in Catalysis 30, 107–113 (2004). https://doi.org/10.1023/B:TOCA.0000029737.89510.22

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  • DOI: https://doi.org/10.1023/B:TOCA.0000029737.89510.22

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