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A New [5]Ferrocenophane Containing a N–Si–O–Si–N Bridge. Molecular Structure in the Solid State and in Solution

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Abstract

The reaction of 1,1′-diaminoferrocene 1 with 1,3-dichloro-1,1,3,3-tetramethyl-1,3-disiloxane in the presence of triethylamine gave the new 1,5,3,2,4-diazaoxadisila[5]ferrocenophane, which was characterized in the solid state by X-ray structural analysis, 13C and 29Si MAS NMR spectroscopy, and in solution by [1H], [13C], [15N], and [29Si]NMR spectroscopy. The ideal ferrocene geometry is slightly distorted, and the cycle containing the heteroelements N, Si, and O is nonplanar. In solution, NMR spectra indicate dynamic processes which may involve both the cyclopentadienyl rings and ring inversion.

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Authors and Affiliations

  1. Anorganische Chemie II, Universität Bayreuth, D-95440, Bayreuth, Germany

    Bernd Wrackmeyer, Elena V. Klimkina & Wolfgang Milius

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  1. Bernd Wrackmeyer
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  2. Elena V. Klimkina
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  3. Wolfgang Milius
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Correspondence to Bernd Wrackmeyer.

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Wrackmeyer, B., Klimkina, E.V. & Milius, W. A New [5]Ferrocenophane Containing a N–Si–O–Si–N Bridge. Molecular Structure in the Solid State and in Solution. Structural Chemistry 15, 333–337 (2004). https://doi.org/10.1023/B:STUC.0000026749.09865.39

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  • DOI: https://doi.org/10.1023/B:STUC.0000026749.09865.39

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