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A dinuclear oxygen-bridged Schiff base iron(III) complex derived from N,N′-bis(4-methoxy-2-hydroxybenzylidene)-2,2-dimethylpropane-1,3-diamine

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Abstract

The μ-oxo-bridged Fe(III) dimer complex [{Fe(4-MeOL1)}2(μ-O)]∙HOCH3, (H2-4-MeOL1 = N,N′-bis(4-methoxy-2-hydroxybenzylidene)-2,2-dimethylpropane-1,3-diamine), 1 is synthesized and characterized by single crystal X-ray diffraction. Complex 1 contains a [{Fe(4-MeOL1)}2(μ-O)] dimeric unit with a methanol solvent molecule of crystallization. Each Fe(III) ion has a distorted square-pyramidal coordination geometry. In the basal plane, the Fe(III) atom is coordinated by two N and two O atoms of the Schiff base ligand. The apical position is occupied by a bridging O2– ion, linking another Fe(III) ion in the complex. There are intermolecular C–H…O and C–H…π interactions among the dinuclear complexes.

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Authors and Affiliations

  1. Dept. Property Protect & Safety, Suleyman Demirel University, Sutculer Prof. Dr. Hasan Gurbuz Vocat Sch., Isparta, Turkey

    A. Karahan

  2. Alanya Engineering Faculty, Materials Science and Engineering, Akdeniz University, Alanya, Antalya, Turkey

    R. Kurtaran

  3. Department of Physics, Faculty of Science and Art, Balikesir University, Balıkesir, Turkey

    Y. Yahsi, E. Gungor & H. Kara

  4. Department of Physics, Faculty of Science, Mugla Sıtkı Koçman University, Mugla, Turkey

    H. Kara

Authors
  1. A. Karahan
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  2. R. Kurtaran
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  3. Y. Yahsi
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  4. E. Gungor
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  5. H. Kara
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Correspondence to A. Karahan.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 770-775, May-June, 2016.

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Karahan, A., Kurtaran, R., Yahsi, Y. et al. A dinuclear oxygen-bridged Schiff base iron(III) complex derived from N,N′-bis(4-methoxy-2-hydroxybenzylidene)-2,2-dimethylpropane-1,3-diamine. J Struct Chem 57, 731–736 (2016). https://doi.org/10.1134/S0022476616040156

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  • DOI: https://doi.org/10.1134/S0022476616040156

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