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The Application of Operator Formalism for Describing Experiments in Multipole Spin Systems under Multipulse Actions

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Abstract

An operator formalism is developed which allows multi-pulse actions on scalar-coupled spin systems with quadrupole nuclei to be analyzed. The formulas describing the evolution of angular-momentum operators under the action of a spin-spin interaction Hamiltonian are derived. The calculation of an NMR-spectrum for scalar-coupled multipole spin systems of the AX (A = 1/2, X = 1, 3/2) and AMX (M = 1, X = 1) types is presented and the polarization transfer processes under multi-pulse action are examined as examples of application of the operator formalism. A series of pulse sequences is proposed which allows individual longitudinal spin orders to be observed.

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REFERENCES

  1. O. W. Sorensen, G. W. Eich, M. H. Levitt, et al., Progress NMR Spectros., 16, 133 (1983).

    Google Scholar 

  2. M. A. Howarth, L. Y. Lian, G. E. Hawkes, and K. D. Sales, J. Magn. Reson., 68, 433 (1986).

    Google Scholar 

  3. L. E. Kay and R. E. D. McClung, J. Magn. Reson., 77, 258 (1988).

    Google Scholar 

  4. R. Ernst, J. Bodenhausen, and A. Vokawn, NMR in One and Two Dimensions [Russian translation], Mir, Moscow, 1990.

    Google Scholar 

  5. N. Chandrakumar, Spin-1 NMR in NMR Basic Principles and Progress, Springer Verlag, Berlin, 1996.

    Google Scholar 

  6. L. Bidenkharn and J. Lauk, Angular Momentum in Quantum Mechanics [Russian translation], Mir, Moscow, 1984.

    Google Scholar 

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Authors and Affiliations

  1. Kaliningrad State University, Russia

    G. S. Kupriyanova

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  1. G. S. Kupriyanova
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Kupriyanova, G.S. The Application of Operator Formalism for Describing Experiments in Multipole Spin Systems under Multipulse Actions. Russian Physics Journal 46, 1245–1252 (2003). https://doi.org/10.1023/B:RUPJ.0000028151.41964.8c

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  • DOI: https://doi.org/10.1023/B:RUPJ.0000028151.41964.8c

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