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Fragmentation at Electron Impact of Nitro Derivatives of 1,2,4-Oxadiazole and 1,2,3-Triazole

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Abstract

Mass spectra were investigated of a series of 3-aryl-5-(nitromethyl)-1,2,4-oxadiazole derivatives and of N-methylated (benzylated) isomeric 4-(dinitromethyl)-1,2,3-triazoles. The principal fragmentation processes of these compounds involve the heterocycle opening and/or liberation of nitrogen-containing fragments followed by formation of the most stable fragment ions.

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Authors and Affiliations

  1. Astrakhan State University, Astrakhan, 414056, Russia

    A. G. Tyrkov, N. A. Solov'ev, T. D. Ladyzhnikova & K.V. Altukhov

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  1. A. G. Tyrkov
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  2. N. A. Solov'ev
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  3. T. D. Ladyzhnikova
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  4. K.V. Altukhov
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Tyrkov, A.G., Solov'ev, N.A., Ladyzhnikova, T.D. et al. Fragmentation at Electron Impact of Nitro Derivatives of 1,2,4-Oxadiazole and 1,2,3-Triazole. Russian Journal of Organic Chemistry 40, 1151–1155 (2004). https://doi.org/10.1023/B:RUJO.0000045897.50456.f7

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  • DOI: https://doi.org/10.1023/B:RUJO.0000045897.50456.f7

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