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Spectroscopic and Dielcometric Study of the Kinetics of Alcoholysis of Trichloroacetyl Chloride with Butanol

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Abstract

The kinetics of alcoholysis of trichloroacetyl chloride with butanol in carbon tetrachloride were studied by dielcometry and IR spectroscopy. The reaction is reversible, and it involves intermediate formation of 1-butoxy-1,2,2,2-tetrachloroethanol and 1,1,2,2,2-pentachloroethanol.

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Authors and Affiliations

  1. Samara State University, Samara, Russia

    V. V. Varfolomeeva, V. A. Terent'ev & A. V. Bulanova

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  1. V. V. Varfolomeeva
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  2. V. A. Terent'ev
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  3. A. V. Bulanova
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Varfolomeeva, V.V., Terent'ev, V.A. & Bulanova, A.V. Spectroscopic and Dielcometric Study of the Kinetics of Alcoholysis of Trichloroacetyl Chloride with Butanol. Russian Journal of General Chemistry 73, 1799–1802 (2003). https://doi.org/10.1023/B:RUGC.0000018658.61663.42

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  • DOI: https://doi.org/10.1023/B:RUGC.0000018658.61663.42

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