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Stevens Rearrangement of Anilinium Salts By the Action Sodium Carbonate Hexahydrate

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Abstract

Anilinium salts containing an allyl-like group together with various functionally substituted receiving groups undergo Stevens rearrangement by the action of sodium carbonate hexahydrate in the absence of a solvent. As a result, both N-methylaniline derivatives and nucleophilic substitution products are formed.

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REFERENCES

  1. Karapetyan, V.E., Kocharyan, S.T., and Babayan, A.T., Arm. Khim. Zh., 1990, vol. 43, no. 5, p. 319.

    Google Scholar 

  2. Jones, G.C., Beard, W.Q., and Hauser, C.R., J. Org. Chem., 1963, vol. 28, no. 1, p. 199.

    Google Scholar 

  3. Giumanini, A.G. and Lepley, A.R., Congresse National della Societa Chemica Italliana, Padova, 1968, comn. XIII/25.

  4. Hellman, H. and Unseld, W., Justus Liebigs Ann. Chem., 1968, vol. 631, nos. 1-3, p. 82.

    Google Scholar 

  5. Giumanini, A.G. and Lepley, A.R., Bull. Chem Soc. Jpn., 1959, vol. 42, p. 2359.

    Google Scholar 

  6. Babayan, A.T., Torosyan, G.O., Geokchyan, G.G., Mkrtchyan, R.S., Takmazyan, K.Ts., and Mushegyan, A.V., Khim. Geterotsikl. Soedin., 1984, no. 4, p. 475.

  7. Babayan, A.T., Martirosyan, G.T., and Grigoryan, Dzh.V., Dokl. Akad. Nauk Arm. SSR, 1962, vol. 35, no. 3, p. 129.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Armenia, Erevan, Armenia

    L. G. Shakhbazyan, A. V. Babakhanyan, Dzh. V. Grigoryan & S. T. Kocharyan

  2. Abovyan Armenian State Pedagogical University, Erevan, Armenia

    L. G. Shakhbazyan, A. V. Babakhanyan, Dzh. V. Grigoryan & S. T. Kocharyan

Authors
  1. L. G. Shakhbazyan
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  2. A. V. Babakhanyan
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  3. Dzh. V. Grigoryan
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  4. S. T. Kocharyan
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Shakhbazyan, L.G., Babakhanyan, A.V., Grigoryan, D.V. et al. Stevens Rearrangement of Anilinium Salts By the Action Sodium Carbonate Hexahydrate. Russian Journal of General Chemistry 73, 1608–1610 (2003). https://doi.org/10.1023/B:RUGC.0000016031.82173.59

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  • DOI: https://doi.org/10.1023/B:RUGC.0000016031.82173.59

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