Abstract
Treatment of a tertiary N-oxide with an activating agent such as acetic anhydride, resulting in rearrangement where an N,N-disubstituted acetamide and an aldehyde are generated.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Polonovski, M.; Polonovski, M. Bull. Soc. Chim. Fr. 1927, 41, 1190–1208.
Michelot, R. Bull. Soc. Chim. Fr. 1969, 4377–4385.
Lounasmaa, M.; Karvinen, E.; Koskinen, A.; Jokela, R. Tetrahedron 1987, 43, 2135– 2146.
Tamminen, T.; Jokela, R.; Tirkkonen, B.; Lounasmaa, M. Tetrahedron 1989, 45, 2683–2692.
Grierson, D. Org. React. 1990, 39, 85–295. (Review).
Morita, H.; Kobayashi, J. J. Org. Chem. 2002, 67, 5378–5381.
McCamley, K.; Ripper, J. A.; Singer, R. D.; Scammells, P. J. J. Org. Chem. 2003, 68, 9847–9850.
Nakahara, S.; Kubo, A. Heterocycles 2004, 63, 1849–1854.
Thavaneswaran, S.; Scammells, P. J. Bioorg. Med. Chem. Lett. 2006, 16, 2868–2871.
Volz, H.; Gartner, H. Eur. J. Org. Chem. 2007, 2791–2801.
Pacquelet, S.; Blache, Y.; Kimny, T.; Dubois, M.-A. L.; Desbois, N. Synth. Commun. 2013, 43, 1092–1100.
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Li, J.J. (2014). Polonovski reaction. In: Name Reactions. Springer, Cham. https://doi.org/10.1007/978-3-319-03979-4_218
Download citation
DOI: https://doi.org/10.1007/978-3-319-03979-4_218
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-03978-7
Online ISBN: 978-3-319-03979-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)