Abstract
A two-dimensional mathematical model for the transport of reactants in a fuel cell with a solid polymer electrolyte is developed. The model is used for analyzing spatial distributions of the concentration of reactants and current density over the cell. The effect of the catalytic-layer activity, reactant speed, bipolar-plate geometry, thickness and porosity of current collector and/or gas-diffusion sublayer, and the reaction mixture composition on the fuel cell efficiency is estimated theoretically and experimentally.
Similar content being viewed by others
REFERENCES
Wu, Y., Sun, H., and Liu, H., Proc. XIII World Hydrogen Energy Conf., Beijing, 2000, vol. 2, p. 858.
You, L., Liu, H., Kakac, S., and Veziroglu, T.N., Proc. XIII World Hydrogen Energy Conf., Beijing, 2000, vol. 2, p. 932.
Sun, H., Wu, Y., and Liu, H., Proc. XIII World Hydrogen Energy Conf., Beijing, 2000, vol. 2, p. 1281.
Gurau, V. and Liu, H.T., Proc. XII World Hydrogen Energy Conf., Buenos Aires, 1998, vol. 2, p. 1707.
Dohle, H., Kornyshev, A.A., Kulikovsky, A.A., Mergel, J., and Stolten, D., Electrochem. Commun., 2001, vol. 3, p. 73.
Kornyshev, A.A. and Kulikovsky, A.A., Electrochim. Acta, 2001, vol. 46, p. 4389.
Dohle, H., Bewer, T., Mergel, J., Neitzel, R., and Stolten, D., Proc. Fuel Cell Seminar, Portland, 2000, p. 130.
Scott, K., Taama, W.M., and Argyropoulos, P., J. Appl. Electrochem., 1998, vol. 28, p. 1389.
Grigor'ev, S.A., Alanakyan, Yu.R., Rusanov, V.D., and Fateev, V.N., Mass Transfer in Fuel Cells with Solid Polymer Electrolytes, Preprint of Kurchatov Inst., Moscow, 2000, no. IAE-6173/13.
Baranov, I.E., Grigor'ev, S.A., Porembskii, V.I., and Tsypkin, M.A., Abstracts of Papers, Vseros. seminar “Toplivnye elementy i energoustanovki na ikh osnove” (All-Russia Workshop on Fuel Cells and Power Installa-tions on Their Basis), Obninsk, 2000, p. 68.
Grigoriev, S.A. and Fateev, V.N., Proc. XIII World Hydrogen Energy Conf., Beijing, 2000, vol. 2, p. 938.
Grigor'ev, S.A., Alanakyan, Yu.R., Fateev, V.N., and Rusanov, V.D., Dokl. Akad. Nauk, 2002, vol. 382, p. 488.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Grigor'ev, S.A., Kalinnikov, A.A., Porembskii, V.I. et al. Optimization of Mass Transfer Processes in the Zone of the Air Electrode of a Fuel Cell with a Solid Polymer Electrolyte. Russian Journal of Electrochemistry 40, 1188–1192 (2004). https://doi.org/10.1023/B:RUEL.0000048652.16015.12
Issue Date:
DOI: https://doi.org/10.1023/B:RUEL.0000048652.16015.12