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Drift Mobility of Electrons in Pyrazoline-Containing Copolymers

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Abstract

Drift mobility of electrons in copolymers containing pyrazolyl fragment in the main or side chain of the copolymer is studied experimentally using the time-of-flight method. The mobility is an exponential function of the applied electric field, and its values for the copolymers range from 5 × 10–7 to 2 × 10–5 cm2 V–1 s–1 at the field strength ranging from 5 × 104 to 1 × 106 V cm–1. Based on the measured mobilities and the molecule parameters, which were obtained by a PM3 quantum-chemical calculation, the role of copolymer fragments in the transport of charge carriers is discussed.

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Authors and Affiliations

  1. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    A. R. Tameev & A. V. Vannikov

  2. Institute of Optoelectronic Technology, Beijing Jiaotong University, 100044, China

    Z. He

  3. Napier University, Colinton Road 10, Edinburgh, EH10 5DT, UK

    G. H. W. Milburn

  4. Chemical Department, University of Agriculture, Krakow, 31129, Poland

    A. Danel & P. Tomasik

Authors
  1. A. R. Tameev
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  2. Z. He
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  3. G. H. W. Milburn
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  4. A. Danel
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  5. P. Tomasik
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  6. A. V. Vannikov
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Tameev, A.R., He, Z., Milburn, G.H.W. et al. Drift Mobility of Electrons in Pyrazoline-Containing Copolymers. Russian Journal of Electrochemistry 40, 359–363 (2004). https://doi.org/10.1023/B:RUEL.0000019677.03172.32

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  • DOI: https://doi.org/10.1023/B:RUEL.0000019677.03172.32

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