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Methodological Aspects of the Partial Charge Transfer in the Adsorption of Anions. Part II

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Abstract

The partial charge transfer coefficient and the electrosorption valence of anions on metals, as well as the role of electron tunneling in the formation of contact electric resistance (CER) signal are discussed. The CER value is shown to depend on the potential (E), the surface coverage with adsorbate particles, and their apparent charge. Bell-shaped CER–E curves of copper, silver, and gold in solutions containing halide ions are obtained. The maxima of these curves (E max) correspond to the beginning of a substantial charge transfer and depend on the metal, anion, and its concentration. At E < E max, halides adsorb without a noticeable charge transfer; while in a range of E max + 0.1 V, the transfer is almost complete. On a chosen metal, E max increases in a series of anions: I– < Br– ≪ Cl–. For a chosen anion (e.g., I–), it increases in a series of metals: Cu ≤ Ag ≪ Au. A correlation between the charge transfer of the adsorbed anions and the adsorption of the solvent, as well as the surface reconstruction of monocrystal electrodes, is discussed. The results are compared to the literature data.

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  1. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. A. Marichev

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  1. V. A. Marichev
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Marichev, V.A. Methodological Aspects of the Partial Charge Transfer in the Adsorption of Anions. Part II. Protection of Metals 40, 169–186 (2004). https://doi.org/10.1023/B:PROM.0000021614.76163.81

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  • DOI: https://doi.org/10.1023/B:PROM.0000021614.76163.81

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