Abstract
The diffusion kinetic regularities of the metal ionization processes in regard to the anionic composition of the electrolyte have been investigated. Analytical relations for studying processes of anodic dissolution involving labile complexes with the anions of the medium that reflect the nature of limiting current, Tafel slopes, and orders of reaction have been obtained. The mechanism of phase layers formation in presence of organic ligands and corresponding theoretical model representing the polarization resistance evolution during the film growth process has been discussed. Established kinetic relations constitute a theoretical basis for the analysis of the dynamic electrochemical systems with phase layers formation as advanced surface engineering and functionalization technique.
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Acknowledgements
This chapter contains substantial amount of results obtained under supervision of Professor Dmytro Tkalenko. Over the years, he dedicated most of his energy to a great honor of finding and solving scientific challenges in the field of electrochemical kinetics of molten salts and corrosion science. His valuable contribution to a scientific knowledge puts him in a line with the most remarkable members of Kyiv Electrochemical School.
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Vyshnevska, Y.P., Brazhnyk, I.V. (2023). Kinetic Regularities of the Interphase Diffusion-Controlled Processes Within Thin Film Formation. In: Fesenko, O., Yatsenko, L. (eds) Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications . Springer Proceedings in Physics, vol 279. Springer, Cham. https://doi.org/10.1007/978-3-031-18096-5_34
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