Skip to main content
SpringerLink
Log in

Reaction products between sodium diphenyl -amine-4-sulfonate and hydrated LaCl3

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

This paper presents the reactions of synthesis between the ligand sodium diphenylamine-4-sulfonate and the lanthanum(III) chloride hydrated. The compounds (LaCl3)2·(C12H10NSO3Na)3·2(CH3CH2OH) (A) and (LaCl3)·(C12H10NSO3Na)·(CH3CH2OH)·12H2O (B) were obtained using the solvents ethanol and methanol (synthesis A) and ethanol and water (synthesis B). The produced compounds and the ligand were characterized by thermogravimetric and differential thermogravimetric analysis, IR spectroscopy and elemental analysis of sodium, carbon, hydrogen, nitrogen, sulfur, chlorine and lanthanum, whereas the residues from thermal decomposition were investigated by X-ray diffractometry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. A. Jeknavorian, Md. Mabud, E. F. Barry and J. J. Litzau, J. Anal. Appl. Pyrol., 46 (1998) 8.

    Article  Google Scholar 

  2. A. De, A. Bhattacharya and S. Das, Polymer, 37 (1996) 19.

    Article  Google Scholar 

  3. G. Cao and T. E. Mallouck, Inorg. Chem., 14 (1991) 34.

    Google Scholar 

  4. T. J. Pinnavania, Science, 220 (1983) 365.

    Google Scholar 

  5. A. Eckardt, I. Riff and J. Weaver, Lub. Eng., 53 (1997) 17.

    Google Scholar 

  6. K. M. Mikulan and N. Ross, Lub. Eng., 55 (1999) 21.

    CAS  Google Scholar 

  7. A. E. H. Hamid, A. A. M. Wedad, Sk. Naguib and A. G. Nader, Ind. Eng. Chem. Res., 32 (1993) 1710.

    Article  Google Scholar 

  8. M. T. Nguyen, P. Kasai, J. L. Miller and A. F. Diaz, Macromolecules, 27 (1994) 3625.

    Article  CAS  Google Scholar 

  9. V. Prevost, A. Petit and F. Pla, Synth. Met., 104 (1999) 79.

    Article  CAS  Google Scholar 

  10. K. A. Gschneidner and L. R. Eyring, Handbook on the Physics and Chemistry of Rare Earths Non-Metallic Compounds, 3 (1979) 208.

    Google Scholar 

  11. B. Sun, Y. Zhao, J. G. Wu, Q. C. Yang and G. X. Xu, J. Mol. Struct., 470 (1998) 63.

    Article  Google Scholar 

  12. W. Brzyska and W. Ozga, J. Therm. Anal. Cal., 70 (2002) 467.

    Article  CAS  Google Scholar 

  13. K. Egashira, Y. Yoshimura and Y. Susuki, J. Therm. Anal. Cal., 71 (2003) 501.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Química, Universidade Federal do Espírito Santo, 29060-900, Vitória -, ES, Brazil E-mail

    L. C. Machado, A. A. L. Marins, E. J. B. Muri, J. A. S. Lacerda, V. O. Balthar & P. F. Fulvio

  2. Departamento de Física, Universidade Federal do Espírito Santo, 29060-900, Vitória -, ES, Brazil

    J. C. C. Freitas

Authors
  1. L. C. Machado
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. L. Marins
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. J. B. Muri
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. A. S. Lacerda
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. O. Balthar
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. P. F. Fulvio
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. J. C. C. Freitas
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. C. Machado.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Machado, L.C., Marins, A.A.L., Muri, E.J.B. et al. Reaction products between sodium diphenyl -amine-4-sulfonate and hydrated LaCl3 . Journal of Thermal Analysis and Calorimetry 75, 615–621 (2004). https://doi.org/10.1023/B:JTAN.0000027153.24401.31

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JTAN.0000027153.24401.31

Search

Navigation