Skip to main content
SpringerLink
Log in

Modified methods to synthesize of 1,8-bis[2-(diphenylphosphoryl)phenoxy]-3,6-dioxaoctane (L). Crystal structure and vibration spectra of [LiL]ClO4·2C6H6

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Modified methods to synthesize, 1,8-bis[2-diphenylphosphoryl)phenoxy]-3,6-dioxaoctane phosphoryl podand (L), an effective complexing agent for the lithium cation, is reported. The possibility to use the phase-transfer catalysis and microwave irradiation is shown. The crystal structure of coordination complex [LiL]ClO4·2C6H6 is determined by X-ray diffraction analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Plyushchev, V.E., and Stepin, B.D., Khimiya i tekhnologiya litiya, rubidiya i tseziya (Chemistry and Technology of Lithium, Rubidium, and Ccesium), Moscow: Khimiya, 1970, p. 11.

    Google Scholar 

  2. Brown, K.M., and Tracy, D.K., Therap. Adv. Psychopharmacol., 2013, vol. 3, no. 3, p. 163. DOI: 10.1177/2045125312471963.

    Article  CAS  Google Scholar 

  3. Izatt, R.M., Bradshow, J.S., Nielsen, S.A., Lamb, J.D., and Christensen, J.J., Chem. Rev., 1985, vol. 85, no. 4, p. 271. DOI: 10.1021/cr00068a003.

    Article  CAS  Google Scholar 

  4. Evreinov, V.I., Baulin, V.E., Vostroknutova, Z.N., Safronova, Z.V., Krashakova, I.B., Syundyukova, V.Kh., and Tsvetkov, E.N., Izv. Akad. Nauk SSSR, Ser. Khim., 1991, no. 9, p. 1992.

    Google Scholar 

  5. Evreinov, V.I., Baulin, V.E., Vostroknutova, Z.N., Bondarenko, N.A., Syundyukova, V.Kh., and Tsvetkov, E.N., Izv. Akad. Nauk SSSR, Ser. Khim., 1989, no. 9, p. 1990.

    Google Scholar 

  6. Tsvetkov, E.N., Syundyukova, V.Kh., and Baulin, V.E., Zh. Obshch. Khim., 1987, vol. 57, no. 11, p. 2456.

    CAS  Google Scholar 

  7. Timmler, K., Harry, D., and Thewissen, M.W., Inorg. Chim. Acta, 1985, vol. 100, no. 2, p. 235. DOI: 10.1016/S0020-1693(00)85291-3.

    Article  Google Scholar 

  8. Evreinov, V.I., Vostroknutova, Z.N., Baulin, V.E., Bondarenko, N.A., Syundyukova, V.Kh., and Tsvetkov, E.N., Zh. Obshch. Khim., 1989, vol. 59, no. 1, p. 67.

    CAS  Google Scholar 

  9. Baulin, V.E., Cand. Sci. (Chem.) Dissertation, Chernogolovka, 1988.

    Google Scholar 

  10. Minacheva, L.Kh., Baulin, V.E., and Sakharova, V.G., Koord. Khim., 1995, vol. 21, no. 3, p. 236.

    Google Scholar 

  11. Minacheva, L.Kh., Ivanova, I.S., Tsivadze, A.Yu., and Sergienko, V.S., Dokl. Chem., 2001, vol. 377, no. 1, p. 65.

    Article  Google Scholar 

  12. Minacheva, L.Kh., Ivanova, I.S., Kireeva, I.K., Sakharova, V.G., Tsivadze, A.Yu., and Porai-Koshits, M.A., Koord. Khim., 1993, vol. 19, no. 3, p. 185.

    CAS  Google Scholar 

  13. Steed, J.W. and Atwood, J.L., Supramolecular Chemistry, Wiley, 2009.

    Book  Google Scholar 

  14. Allen, F.H., Kennard, O., and Taylor, R., Acc. Chem. Res., 1983, vol. 16, no. 5, p. 146. DOI: 10.1021/ar00089a001.

    Article  CAS  Google Scholar 

  15. Hichcoock, P.B., Hulkes, A.G., Lappert, M.F., and Protchenko, A.V., Inorg. Chim. Acta, 2006, vol. 359, p. 2998. DOI: 10.1016/j.ica.2005.12.063.

    Article  Google Scholar 

  16. Tahiri, M., Doppelt, P., Fischer, J., and Weiss, R., Inorg. Chim. Acta, 1987, vol. 127, p. L1. DOI: 10.1016/S0020-1693(00)88348-6.

    Article  CAS  Google Scholar 

  17. APEX2 (V. 2009, 5-1), SAINT (V7.60A), SADABS (2008/1), Bruker AXS Inc., Madison, Wisconsin, USA, 2008–2009.

  18. Altomare, A., Cascarano, G., Giacovazzo, C., and Guagliardi, A., J. Appl. Crystallogr., 1993, vol. 26, no. 3, p. 343. DOI: 10.1107/S0021889892010331.

    Article  Google Scholar 

  19. Sheldrick, G.M., Acta Crystallogr. (A), 2008, vol. 64, no. 1, p. 112. DOI: 10.1107/S0108767307043930.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. E. Baulin, I. S. Ivanova, E. N. Pyatova, E. S. Krivorot’ko & A. Yu. Tsivadze

  2. Kurnakov Institute of General and Inorganic Chemistry, Moscow, Russia

    I. S. Ivanova, I. N. Polyakova & E. N. Pyatova

  3. Institute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    V. E. Baulin

Authors
  1. V. E. Baulin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. S. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. N. Polyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. N. Pyatova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. S. Krivorot’ko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Yu. Tsivadze
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. E. Baulin.

Additional information

Original Russian Text © V.E. Baulin, I.S. Ivanova, I.N. Polyakova, E.N. Pyatova, E.S. Krivorot’ko, A.Yu. Tsivadze, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 4, pp. 659–665.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Baulin, V.E., Ivanova, I.S., Polyakova, I.N. et al. Modified methods to synthesize of 1,8-bis[2-(diphenylphosphoryl)phenoxy]-3,6-dioxaoctane (L). Crystal structure and vibration spectra of [LiL]ClO4·2C6H6 . Russ J Gen Chem 85, 899–905 (2015). https://doi.org/10.1134/S1070363215040234

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363215040234

Keywords

Search

Navigation