Abstract
Results of a thermodynamic and geometric-topological analysis of the subsolidus structure of the BaO – Al2O3 – Fe2O3 – SiO2 system at temperatures above 1381 K are reported. Tetrahedratization of the system, with due regard for the existing high-temperature phases, is carried out. Data for solid-state reactions in the system obtained by thermodynamic and geometric-topological calculations are presented. Technological implications in the synthesis a new class of barium-containing cements with allowance for the specific subsolidus structure (associated with reversible solid-state reactions in ternary subsystems and the quaternary BaO – Al2O3 – Fe2O3 – SiO2 system proper) are discussed.
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REFERENCES
G. N. Shabanova, I. V. Gurenko, and S. N. Bykanov, “Section BaO – BaFe2O4 – BaSiO3 studied in the BaO – Fe2O3 – SiO2 system,” in: Vestnik Kharkov State Politechnical University (KhGPU), Issue 28 [in Russian], KhGPU, Kharkov (1999), pp. 56 – 59.
G. N. Shabanova, V. V. Taranenkova, A. N. Korogodskaya, and E. V. Khristich, “Concerning the structure of the BaO – Al2O3 – SiO2 system,” Steklo Keram., No. 2, 12 – 15 (2003).
G. N. Shabanova, I. V. Gurenko, and S. N. Bykanov, “Thermodynamic analysis of reactions in the BaO – Fe2O3 – SiO2 system,” in: A. S. Berezhnoi Ukrainian Research Institute for Refractories JSC. Collection of Research Papers [in Russian], Karavella, Kharkov (2001), pp. 120 – 126.
G. N. Shabanova, V. V. Taranenkova, and S. N. Bykanov, “On the existence of a ternary compound Ba2AlFeO5 in the BaO – Al2O3 – Fe2O3 system,” in: Problems in Chemistry and Chemical Engineering. UGKhTU, No. 1 [in Russian], Novaya Ideologiya, Dnepropetrovsk (2002), pp. 60 – 63.
G. N. Shabanova and S. N. Bykanov, “Structure of the BaO – Al2O3 – Fe2O3 system,” Ogneup. Tekh. Keram., No. 7 – 8, 21 – 24 (2002).
G. N. Shabanova and I. V. Gurenko, “A structural study of the BaO – Fe2O3 W SiO2 system,” Vestnik NTU KhPI, Vol. 2, No. 9 [in Russian], Kharkov (2002), pp. 27 – 31.
A. S. Berezhnoi, Ya. N. Pitak, A. D. Ponomarenko, and N. P. Sobol', Physicochemical Systems of High-Melting Nonmetallic and Silicate Materials [in Russian], NMK VO, Kiev (1992).
V. I. Babushkin, G. M. Matveev, and O. P. Mchedlov-Petrosyan, Thermodynamics of Silicates [in Russian], Stroiizdat, Moscow (1986).
L. A. Reznitskii, “Enthalpy of formation for compounds with a structure of magnetoplumbite Mfe12O19 (M = Pb, Sr, Ba) and barium ferrites,” Zh. Neorg. Khim., 66, Issue 7 (1992).
V. P. Glushko, Thermodynamic Constants of Materials. Issue IX [in Russian], USSR Academy of Sciences, Moscow (1974).
R. Barany, E. G. King, and S. S. Todd, J. Am. Ceram. Soc., No. 79, 3639 – 3641 (1957).
G. N. Shabanova, N. V. Kazmina, and S. N. Bykanov, “Thermodynamic analysis of mutual reactions in the BaO – Al2O3 – SiO2 system,” in: Vestnik KhGPU, Issue 33 [in Russian], KhGPU, Kharkov (1999), pp. 29 – 32.
F. I. Strigunov and V. N. Alekseev, “Astudy of the reactions in a system containing BaS, SiO2, Al2 O3, Fe2O3, and H2O,” Zh. Prikl. Khim. 68, Issue 11, 2445 – 2447 (1975).
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Shabanova, G.N. Specific Features of the Subsolidus Structure of the BaO – Al2O3 – Fe2O3 – SiO2 System. Part 1. Subsolidus Structure of the BaO – Al2O3 – Fe2O3 – SiO2 System at Temperatures Above 1381 K. Refractories and Industrial Ceramics 44, 254–259 (2003). https://doi.org/10.1023/A:1027391701188
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DOI: https://doi.org/10.1023/A:1027391701188