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Limiting Electroconductivity and Structure of Molten Chlorides of Alkaline-Earth Metals

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Abstract

It is established experimentally that the electroconductivity of individual molten chlorides of calcium, strontium, and barium increases with the electric field strength and reaches limiting values, which are dependent on the salt nature and the temperature. The limiting electroconductivity of molten calcium and strontium chlorides satisfactorily obeys the Nernst–Einstein relationship. The relaxation kinetics of excess conductivity induced by high-voltage pulsed discharges is studied. The relaxation time is equal to about 104 s.

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Authors and Affiliations

  1. Dagestan State University, Makhachkala, Dagestan, Russia

    O. M. Shabanov, A. O. Magomedova & S. A. Dzhamalova

Authors
  1. S. M. Gadzhiev
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  2. O. M. Shabanov
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  3. A. O. Magomedova
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  4. S. A. Dzhamalova
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Gadzhiev, S.M., Shabanov, O.M., Magomedova, A.O. et al. Limiting Electroconductivity and Structure of Molten Chlorides of Alkaline-Earth Metals. Russian Journal of Electrochemistry 39, 1083–1088 (2003). https://doi.org/10.1023/A:1026171420132

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  • DOI: https://doi.org/10.1023/A:1026171420132

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