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Alcohols, Ethers, and Esters with Peroxy Groups Prepared from 2-tert-Butylperoxy-2-methylpentan-4-one

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Abstract

2-tert-Butylperoxy-2-methylpentan-4-one reacts with butyllithium providing saturated tertiary peroxyalcohol, with 1-lithioalkynes, among them lithiooxy- and peroxy-containing, gives rise to the corresponding tertiary acetylene mono- and diperoxyalcohols and diols. The thermal stability of peroxides obtained was evaluated by derivatography.

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Authors and Affiliations

  1. Institute of New Materials Chemistry, Belarussian National Academy of Sciences, Minsk, 220141, Belarus

    A. P. Yuvchenko & E. A. Dikusar

  2. Institute of Physical Organic Chemistry, Belarussian National Academy of Sciences, Minsk, 220072, Belarus

    T. D. Zvereva & V. L. Murashko

Authors
  1. A. P. Yuvchenko
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  2. E. A. Dikusar
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  3. T. D. Zvereva
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  4. V. L. Murashko
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Yuvchenko, A.P., Dikusar, E.A., Zvereva, T.D. et al. Alcohols, Ethers, and Esters with Peroxy Groups Prepared from 2-tert-Butylperoxy-2-methylpentan-4-one. Russian Journal of Organic Chemistry 39, 164–169 (2003). https://doi.org/10.1023/A:1025571715587

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  • DOI: https://doi.org/10.1023/A:1025571715587

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