Abstract
Glass formation in the ZrF4–BaF2–LaF3–AlF3–NaF system is studied by differential thermal analysis at fixed ZrF4 (50–60 mol %) and BaF2 (20–30 mol %) contents. Using stability criteria, the most stable glass compositions are identified.
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REFERENCES
Gur'ev, N.V., Petrovskii, G.T., Stepanov, S.A., et al., Formation and Properties of Glasses in the Systems ZrF4-BaF2-LaF3-AlF3-MeF (Me = Li, Na, Cs), Fiz. Khim. Stekla, 1988, vol. 14, no. 6, pp. 842-847.
Shahriari, M.R., Iqbal, T., Sigel, G.H., and Merberg, G., Synthesis and Characterisations of AlF3-Based Glasses and Optical Fibers, Mater. Sci. Forum, 1988, vol. 32/33, pp. 99-106.
Poulain, M., Multicomponent Fluoride Glasses, J. Non-Cryst. Solids, 1997, vol. 213/214, pp. 40-43.
Mac Farlane, D.R., Javorniczky, J., Newmen, P.I., et al., High Er(III) Content ZBN Glasses for Microchip Laser Application, J. Non-Cryst. Solids, 1997, vol. 213/214, pp. 158-163.
Ferraris, M., Braglia, M., Chiappetta, R., et al., Different Processes for the Preparation of Fluorozirconate Glasses, Mater. Res. Bull., 1990, vol. 25, no. 7, pp. 891-897.
Coon, J. and Shelby, J.E., Effect of Melt History on the Stability and Quality of ZBLAN Glasses, Mater. Sci. Forum, 1988, vol. 32/33, pp. 37-42.
Andrews, L.J., Hall, B.T., Folweiler, R.C., and Moynihan, C.T., In Situ Oxidation of Heavy Metal Fluoride Glasses, Mater. Sci. Forum, 1988, vol. 32/33, pp. 43-48.
Shiryaev, V.S., Crystallization-Induced Microinhomogeneity of ZrF4-BaF2-LaF3-AlF3-NaF and ZrF4-BaF2- LaF3-AlF3-LiF Glasses, Extended Abstract of Cand. Sci. (Chem.) Dissertation, Nizhni Novgorod, 1992.
Bruce, A.J., Atkins, R.M., and Kometani, T.Y., Liquid/ Vapor Equilibria of a ZBLAN Melt at High Temperature, Mater. Sci. Forum, 1988, vol. 32/33, pp. 69-74.
Parker, J.M., Seddon, A.B., and Clare, A.G., Crystallisation of ZrF4-BaF2-NaF-AlF3-LaF3 Glasses, Phys. Chem. Glasses, 1987, vol. 28, no. 1, pp. 4-10.
Babitsyna, A.A., Emel'yanova, T.A., and Fedorov, V.A., Glass-Forming Regions in the NaF-BaF2-LaF3-ZrF4 System, Neorg. Mater., 1997, vol. 33, no. 1, pp. 87-92 [Inorg. Mater. (Engl. Transl.), vol. 33, no. 1, pp. 78-83].
Babitsyna, A.A., Emel'yanova, T.A., and Fedorov, V.A., Glass Formation in the BaF2-AlF3-LaF3-ZrF4 System, Neorg. Mater., 1997, vol. 33, no. 11, pp. 1381-1384 [Inorg. Mater. (Engl. Transl.), vol. 33, no. 11, pp. 1173-1176].
Babitsyna, A.A., Emel'yanova, T.A., and Fedorov, V.A., Glass Formation in the ZrF4-BaF2-AlF3-NaF, ZrF4- BaF2-LaF3-NaF, and ZrF4-BaF2-LaF3-AlF3 Systems, Neorg. Mater., 2002, vol. 38, no. 5, pp. 622-631 [Inorg. Mater. (Engl. Transl.), vol. 38, no. 5, pp. 512-521].
Lecoq, A. and Poulain, M., Etude phénoménologique du r le stabilizateur de l'aluminium dans les verres au tétrafluorure de zirconium, Verres Refract., 1980, vol. 34, no. 3, pp. 333-342.
Matsusita, K., Miura, K., and Komatsu, T., Kinetics of Non-Isothermal Crystallization of Some Fluorozirconate Glasses, Thermochim. Acta, 1985, vol. 88, no. 1, pp. 283-288.
Zhao, X. and Sakka, S., Glass Formation and Crystallisation in Alkali-Containing Fluoride Glasses, J. Non-Cryst. Solids, 1987, vol. 95/96, pp. 487-494.
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Babitsyna, A.A., Emel'yanova, T.A. & Fedorov, V.A. Glass Formation in the ZrF4–BaF2–LaF3–AlF3–NaF System. Inorganic Materials 39, 981–987 (2003). https://doi.org/10.1023/A:1025521708531
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DOI: https://doi.org/10.1023/A:1025521708531