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Characteristics of the Macromolecular Reaction of the Graft Copolymer of Polyvinyl Alcohol and Polyglycidyl Methacrylate with Hydroxyethylamine

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Fibre Chemistry Aims and scope

Abstract

The kinetics of the macromolecular reaction of amination of PVA—PGMA graft copolymer is quantitatively described. The initial rate of the process, order of the reaction rate in amine, and effective activation energy are determined. The effect of the nature of the polymer matrix on the kinetic parameters of conversion of graft PGMA α-oxide groups under the effect of hydroxyethylamine is established.

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Authors and Affiliations

  1. Moscow State Textile University, Russia

    T. V. Druzhinina, I. B. Zhigalov, E. V. Sibeikina & K. I. Kobrakov

Authors
  1. T. V. Druzhinina
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  2. I. B. Zhigalov
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  3. E. V. Sibeikina
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  4. K. I. Kobrakov
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Druzhinina, T.V., Zhigalov, I.B., Sibeikina, E.V. et al. Characteristics of the Macromolecular Reaction of the Graft Copolymer of Polyvinyl Alcohol and Polyglycidyl Methacrylate with Hydroxyethylamine. Fibre Chemistry 35, 105–110 (2003). https://doi.org/10.1023/A:1024834211352

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  • DOI: https://doi.org/10.1023/A:1024834211352

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