Abstract
The radical reactions of copolymerization with vinyl monomers and homopolymerization of synthesized fullerene-containing acrylates are studied. In contrast to the homopolymers, the fullerene-containing copolymers are readily soluble in typical organic solvents. The kinetic parameters of the copolymerization process and molecular-weight characteristics of the resulting products are determined.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. Günes, H. Neugebauer, and N. S. Sariciftci, Chem. Rev. 107, 1324 (2007).
K. M. Coakley and M. D. McGehee, Chem. Mater. 16, 4533 (2004).
Y.-C. Chen, C.-Y. Hsu, and R. Y.-Y. Lin, K.-C. Ho, and J. T. Lin, ChemSusChem 6, 20 (2013).
D. Jariwala, V. K. Sangwan, L. J. Lauhon, T. J. Marks, and M. C. Hersam, Chem. Soc. Rev. 42, 2824 (2013).
A. Bianco and T. D. Ros, in Fullerenes: Principles and Applications, Ed. by F. L. de la Puente and J.-F. Nierengarten (Roy. Soc. Chem., Cambridge, 2012), Vol. 2, p.507.
S. Samal, B.-J. Choi, and K. E. Geckeler, Chem. Commun. 36, 1373 (2000).
D. T. Lai, M. A. Neumann, M. Matsumoto, and J. Sunamoto, Chem. Lett. 29, 64 (2000).
B. de Boer, U. Stalmach, P. F. van Hutten, et al., Polymer 72, 9097 (2001).
H. Sato, D. Matsuda, and K. Ogino, Polym. J. 30, 904 (1998).
S. D. Chambers, T. W. Holcombe, F. Svec, and J. M. J. Frechet, Anal. Chem. 83, 9478 (2011).
X. Chen, B. Gholamkhass, X. Han, G. Vamvounis, and S. Holdcroft, Macromol. Rapid Commun. 28, 1792 (2007).
R. Kh. Yumagulova, Yu. N. Biglova, S. V. Kolesov, and Yu. B. Monakov, Dokl. Chem. 408, 90 (2006).
R. Kh. Yumagulova, Yu. N. Biglova, S. V. Kuznetsov, I. A. Ionova, S. V. Kolesov, and Yu. B. Monakov, Polymer Sci., Ser. A 50, 260 (2008).
S. A. Torosyan, Y. N. Biglova, V. V. Mikheev, Z. T. Khalitova, F. A. Gimalova, and M. S. Miftakhov, Mendeleev Commun. 22, 199 (2012).
G. P. Gladyshev, Polymerization of Vinyl Monomers (Akad. Nauk KazSSR, Alma-Ata, 1964) [in Russian].
A. Gordon and R. Ford, The Chemist’s Companion, A Handbook of Practical Data. Techniques and References (Wiley, New York, 1972).
A. Weissberg, E. Proskauer, J. Riddick, and E. Toops, Organic Solvents (Interscience, New York, 1955; Mir, Moscow, 1958).
S. Shi, K. C. Khemani, Q. C. Li, and F. Wudl, J. Am. Chem. Soc. 114, 10656 (1992).
Y. N. Biglova, A. F. Akbulatov, S. A. Torosyan, D. K. Susarova, A. G. Mustafin, and M. S. Miftakhov, Physica B 458, 114 (2015).
Y. N. Biglova, D. K. Susarova, A. F. Akbulatov, A. G. Mustafin, P. A. Troshin, and M. S. Miftakhov, Mendeleev Commun. 25, 348 (2015).
Y. N. Biglova, D. K. Susarova, A. F. Akbulatov, A. V. Mumyatov, and P. A. Troshin, Mendeleev Commun. 25, 473 (2015).
H. Yan, S. Chen, M. Lu, et al., Mater. Horiz. 1, 247 (2014).
T. Nishimura, K. Takatani, S. Sakurai, K. Maeda, and E. Yashima, Angew. Chem., Int. Ed. 41, 3602 (2002).
W. T. Ford, T. Nishioka, S. C. McCleskey, T. H. Mourey, and P. Kahol, Macromolecules 33, 2413 (2000).
C. E. Bunker, C. E. Lawson, and Y.-P. Sun, Macromolecules 28, 3744 (1995).
T. Cao and S. E. Webber, Macromolecules 29, 3826 (1996).
A. G. Camp, A. Larry, and W. T. Ford, Macromolecules 28, 7959 (1995).
Yu. N. Biglova, Cand. Sci. (Chem.) Dissertation (Inst. Gen. Chem. Ural Sci. Center of RAS, Ufa, 2008).
M. Fineman and S. D. Ross, J. Polym. Sci. 5, 259 (1950).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Yu.N. Biglova, A.G. Mustafin, M.S. Miftakhov, 2017, published in Khimicheskaya Fizika, 2017, Vol. 36, No. 3, pp. 58–64.
Rights and permissions
About this article
Cite this article
Biglova, Y.N., Mustafin, A.G. & Miftakhov, M.S. Physicochemical characteristics of the radical copolymerization of fullerene-containing methacrylates with vinyl monomers. Russ. J. Phys. Chem. B 11, 324–329 (2017). https://doi.org/10.1134/S1990793117020038
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1990793117020038