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Sulfur-containing carboxylic acids. 6. The syntheses of 3,3"-sulfinyldipropionic and 2,2"-sulfinyldiacetic acids

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Abstract

Pure sulfoxides of thiodialiphatic acids were obtained in high yields by oxidation of the corresponding sulfides in organic solvents. 3,3"-Sulfinyldipropionic acid was obtained by the reaction of hydrogen peroxide with thiodipropionic acid in acetone. 2,2"-Sulfinyldiacetic acid was synthesized by the reaction of thiodiglycolic acid with H2O2 in acetone containing acetic acid (26 mol. %). Pure 2,2"-sulfinyldiacetic acid was found to be stable in storage rather than labile as reported previously.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul Vavilova, 119991, Moscow, Russian Federation

    T. P. Vasil"eva

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  1. T. P. Vasil"eva
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Vasil"eva, T.P. Sulfur-containing carboxylic acids. 6. The syntheses of 3,3"-sulfinyldipropionic and 2,2"-sulfinyldiacetic acids. Russian Chemical Bulletin 52, 958–960 (2003). https://doi.org/10.1023/A:1024416829619

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