Abstract
The influence of the chemical composition of the feeding gas mixtures CH4-He on the physical properties of dielectric barrier discharge was investigated experimentally as well as theoretically. Certain changes in the shape of charge-voltage characteristics (Lissajous figures) were observed when the content of He was varied within the range 0–90%. An increase of the He concentration was found to cause monotonous but not linear decrease of the ignition voltage as well as of the burning voltage of the discharge. Measurements of the burning voltage were used to estimate the characteristic energy of electrons in the mixtures under consideration. These estimates were compared with experimentally determined values of the energy consumption for the synthesis of C2H2, C2H4 and C2H6, respectively. It was demonstrated that the observed dependencies of the energy consumption upon He content can be explained taking into consideration the influence of the chemical composition of feeding gas mixture upon the characteristic energy of electrons in the dielectric barrier discharge.
Similar content being viewed by others
References
U. Kogelschatz, B. Eliasson, and W. Egli: inProc. XXIII Int. Conf. on Phenomena in Ionized Gases, Toulouse (France) 1997 (Eds. M.C. Bordage and A. Gleizes), p. 1.
K. V. Kozlov: inContributed Papers of 3rd Int. Symp. on High Pressure Low Temperature Plasma Chemistry (Hakone III), Strassbourg (France) 1991, p. 85.
S. Okazaki, H. Niwa, H. Sugimitsu, M. Kogoma, and T. Inomata: inContributed Papers of 5th Int. Symp. on High Pressure Low Temperature Plasma Chemistry (Hakone V), Milovy (Czech Republic) 1996, p. 26.
C. Yamabe and K. Horii: Memoirs Fac. Engng. Nagoya University41, No. 2, (1989) 127.
R.V.St. Auney: Chimie et Industrie29 (1933) 1011.
Yu.N. Zhitnev and Yu.V. Filippov: Vestnik Moskovskogo Universiteta, Khimiya1 (1967) 8.
H.-E. Wagner, K.V. Kozlov, and P. Michel: Verhandlungen der DPG, Reihe VI33 (1998) 340.
P. Michel, F. Miethke, A. Rutscher, A. Sonnenfeld, and H.-E. Wagner: inContributed Papers of 5th Int. Symp. on High Pressure Low Temperature Plasma Chemistry (Hakone V), Milovy (Czech Republic), 1996, p. 52.
V. Samoilovich, V. Gibalov, and K. Kozlov:Physical Chemistry of the Barrier Discharge, 2nd Edition, DVS-Verlag, Düsseldorf, 1997.
V.L. Bychkov, A.V. Eletskiy, and B.M. Smirnov: Khim. Plazmy (USSR)10 (1983) 146.
K. V. Kozlov: inContributed Papers of 4th Int. Symp. on High Pressure Low Temperature Plasma Chemistry (Hakone IV), Bratislava (Slovakia) 1991, p. 195.
Author information
Authors and Affiliations
Additional information
Dedicated to Prof. Jan Janča on the occasion of his 60th birthday.
The work was supported by the Sonderforschungsbereich 198 “Kinetik partiell ionisierter Plasmen”.
Rights and permissions
About this article
Cite this article
Kozlov, K.V., Michel, P. & Wagner, H.E. Properties of the dielectric barrier discharge in mixtures of methane with helium. Czech J Phys 48, 1199–1207 (1998). https://doi.org/10.1023/A:1022862202402
Received:
Issue Date:
DOI: https://doi.org/10.1023/A:1022862202402