Abstract
Carbonate stability constants for yttrium and all rare earth elements have been determined at 25°C and 0.70 molal ionic strength by solvent exchange and inductively coupled plasma–mass spectrometry (ICP–MS). Measured stability constants for the formation of \({\text{MCO}}_3^ +\) and \({\text{M}}\left( {{\text{CO}}_{\text{3}} } \right)_2^--\) from M3+ are in good agreement with previous direct measurements, which involved the use of radio-chemical techniques and trivalent ions of Y, Ce, Eu, Gd, Tb, and Yb. Direct ICP–MS measurements of \({\text{MCO}}_3^ +\) and \({\text{M}}\left( {{\text{CO}}_{\text{3}} } \right)_2^--\) formation constants are also in general agreement with modeled stability constants for the metals La, Pr, Nd, Sm, Dy, Ho, Er, Tm, and Lu, based on linear-free energy relationship (LFER). The experimental procedures developed in this work can be used for assessing the complexation behavior of other geochemically important ligands such as phosphate, sulfate, and fluoride.
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Liu, X., Byrne, R.H. Comprehensive Investigation of Yttrium and Rare Earth Element Complexation by Carbonate Ions Using ICP–Mass Spectrometry. Journal of Solution Chemistry 27, 803–815 (1998). https://doi.org/10.1023/A:1022677119835
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DOI: https://doi.org/10.1023/A:1022677119835