Skip to main content
Log in

Interaction between REEs and Carbonate Ion

  • CHEMISTRY AND TECHNOLOGY OF RARE, TRACE, AND RADIOACTIVE ELEMENTS
  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

The interaction between rare-earth elements (REEs) and a carbonate ion is studied to examine the possibility of separating REEs during the re-extraction process from an acidic extractant with sodium carbonate solution. It is shown that REEs are effectively re-extracted from an organic phase of imidophosphazene with Na2CO3 solution (2 mol/L), but REEs are not separated into subgroups because of the different solubility of the carbonate precipitates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Er’kina, M.A., Nikovskii, I.A., Tupikov, A.S., and Polyakov, V.A., Production of a phosphazene-containing plasticizer for polymer materials, Usp. Khim. Tekhnol., 2017, vol. 31, no. 11, pp. 149–151.

    Google Scholar 

  2. Bredov, N.S., Gorlov, M.V., Esin, A.S., Bukovckaya, A.A., Kireev, V.V., Sinegribova, O.A., and Ryabochenko, M.D., Linear 2-ethylhexyl imidophosphoric esters as effective rare-earth element extractants, Appl. Sci., 2020, no. 10, pp. 1229–1244. https://doi.org/10.3390/app10041229

  3. Ryabochenko, M.D., Shumikhin, K.V., Sinegribova, O.A., and Chekmarev, A.M., Phosphazenes as collective extractants of REEs, Khim. Tekhnol., 2018, vol. 19, no. 12, pp. 526–568.

    Google Scholar 

  4. Semenov, A.A., Abramov, A.M., Sobol’, Yu.B., Galieva, Zh.N., Galantsev, A.V., and Gerya, V.O., Preparation of Nd2O3 through the extraction separation of rare-earth concentrate recovered from phosphogypsum, Inorg. Mater., 2016, vol. 52, no. 2, pp. 233–236.

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors are grateful to the staff of the Mendeleev Center for Collective Use for their assistance in carrying out this work.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to S. N. Bugaeva or O. A. Sinegribova.

Additional information

Translated by A. Tulyabaew

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bugaeva, S.N., Sinegribova, O.A. Interaction between REEs and Carbonate Ion. Theor Found Chem Eng 56, 942–946 (2022). https://doi.org/10.1134/S0040579522310013

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0040579522310013

Navigation