Electron-Vibrational Interaction and Equilibrium Configurations of the Hydrogen Peroxide Molecule

Abstract

We show that electron-vibrational interaction (Renner effect) in the model of linear configuration of the hydrogen peroxide molecule leads to removal of degeneracy of the electronic state and is the determining factor for the existence of two dissimilar nonplanar equilibrium symmetrically equivalent configurations.

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Correspondence to M. B. Shundalov.

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Shundalov, M.B., Pitsevich, G.A. Electron-Vibrational Interaction and Equilibrium Configurations of the Hydrogen Peroxide Molecule. Journal of Applied Spectroscopy 69, 943–945 (2002). https://doi.org/10.1023/A:1022487109818

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  • nonrigid molecule
  • hydrogen peroxide
  • Renner effect