Abstract
We show that electron-vibrational interaction (Renner effect) in the model of linear configuration of the hydrogen peroxide molecule leads to removal of degeneracy of the electronic state and is the determining factor for the existence of two dissimilar nonplanar equilibrium symmetrically equivalent configurations.
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Shundalov, M.B., Pitsevich, G.A. Electron-Vibrational Interaction and Equilibrium Configurations of the Hydrogen Peroxide Molecule. Journal of Applied Spectroscopy 69, 943–945 (2002). https://doi.org/10.1023/A:1022487109818
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DOI: https://doi.org/10.1023/A:1022487109818