Electron-Vibrational Interaction and Equilibrium Configurations of the Hydrogen Peroxide Molecule


We show that electron-vibrational interaction (Renner effect) in the model of linear configuration of the hydrogen peroxide molecule leads to removal of degeneracy of the electronic state and is the determining factor for the existence of two dissimilar nonplanar equilibrium symmetrically equivalent configurations.

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  1. 1.

    J. M. Fernandez-Sanchez, A. G. Valdenebro, and S. Montero, J. Chem. Phys., 91, 3327–3334 (1989).

    Google Scholar 

  2. 2.

    J.-M. Flaud, C. Camy-Peyret, J. W. C. Johns, and B. Carli, J. Chem. Phys., 91, 1504–1510 (1989).

    Google Scholar 

  3. 3.

    M. B. Shundalov and G. A. Pitsevich, Zh. Prikl. Spektrosk., 68, 699–703 (2001).

    Google Scholar 

  4. 4.

    P. R. Bunker, Molecular Symmetry and Spectroscopy[Russian translation], Moscow (1981).

  5. 5.

    A. V. Burenin, Usp. Fiz. Nauk, 169, 673–685 (1999).

    Google Scholar 

  6. 6.

    I. B. Bersuker, Jahn-Teller Effect and Vibronic Interactions in Modern Chemistry[in Russian], Moscow (1987).

  7. 7.

    G. Herzberg, Electronic Spectra and Electronic Structure of Polyatomic Molecules[Russian translation], Moscow (1969).

  8. 8.

    R. Renner, Z. Phys., 92, 172–183 (1934).

    Google Scholar 

  9. 9.

    A. N. Petelin, Opt. Spektrosk., 29, 1153–1155 (1970).

    Google Scholar 

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Correspondence to M. B. Shundalov.

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Shundalov, M.B., Pitsevich, G.A. Electron-Vibrational Interaction and Equilibrium Configurations of the Hydrogen Peroxide Molecule. Journal of Applied Spectroscopy 69, 943–945 (2002). https://doi.org/10.1023/A:1022487109818

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  • nonrigid molecule
  • hydrogen peroxide
  • Renner effect