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Studying substituent number effects on vibrational energy transfer by time−resolved CARS spectroscopy

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Abstract

Vibrational energy transfer was a key property of chemical reactions that remains deeply understood. In this work, the detail information of vibrational energy transfer in aniline, N,N-dimethylaniline (DMA) and N,N-diethylaniline (DEA) were studied by femtosecond time-resolved coherent anti-Stokes Raman scattering (CARS) spectroscopy, respectively. Low frequency modes of aniline, DMA and DEA were collectively excited, the beats arising from vibrational couplings among these modes were described. With analysis of vibrational coupling, energy transfer flow from one mode to another was visualized. An investigation into the molecular structure and vibrational couplings can be found that vibrational energy transfer is related to vibrational mode symmetry. In addition, substituent groups play an important role in vibrational coupling and energy transfer of aniline, DMA and DEA. A decrease of the number of substituent vibrational modes involved in coupling and energy transfer efficiency with the increase of the amount of relative molecular mass ratio was found out.

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Data availability statement

This manuscript has no associated data or the data will not be deposited. [Authors’ comment: All our data are available from the corresponding author on reasonable request.]

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Acknowledgements

Key Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant NO. 20KJA430005).

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Authors and Affiliations

  1. School of Physics and New Energy, Xuzhou University of Technology, Xuzhou, 221018, China

    Xiaosong Liu, Hui Li & Feng Hu

  2. School of Electrical and Control Engineering, Xuzhou University of Technology, Xuzhou, 221018, China

    Qingxiao Zou

  3. Department of Physics, Harbin Institute of Technology, Harbin, 150001, China

    Weilong Liu

  4. National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, China Academy of Engineering Physics, Mianyang, China

    Yanqiang Yang

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  1. Xiaosong Liu
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  2. Qingxiao Zou
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  3. Hui Li
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  4. Weilong Liu
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  5. Feng Hu
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Both authors have contributed equally to the paper. All authors declare no conflict of interest.

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Correspondence to Xiaosong Liu.

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Liu, X., Zou, Q., Li, H. et al. Studying substituent number effects on vibrational energy transfer by time−resolved CARS spectroscopy. Eur. Phys. J. D 78, 41 (2024). https://doi.org/10.1140/epjd/s10053-024-00830-w

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