Abstract
The formation and fragmentation of negative ions of some N-(methylsulfonyl)anilines upon resonance electron capture have been studied. The formation of long-living molecular ions is due to the presence of the mesyl groups in the molecules. The difference in negative-ion mass spectra of isomeric N-(methylsulfonyl)anilines has been revealed.
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Pikhtovnikov, S.V., Furlei, I.I., Mavrodiev, V.K. et al. Negative-ion mass spectra of some N-mesyl derivatives of o-(cycloalk-2-enyl)-, o-(cycloalk-1-enyl)-, o-(pent-2-enyl)-, o-dibromopentylanilines and (α-bromoalkyl)indolines. Russian Chemical Bulletin 51, 2299–2302 (2002). https://doi.org/10.1023/A:1022108023832
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DOI: https://doi.org/10.1023/A:1022108023832