Abstract
Ferrocenylmethylation and α-ferrocenylethylation of indazole were carried out for the first time. Both reactions afforded two isomers, which were characterized by physical and physicochemical methods, among them by X-ray diffraction analysis. 1-(α-Ferrocenylethyl)indazole is thermally more stable than the 2-substituted isomer. Both isomers serve as ferrocenylalkylating agents with respect to s-triazole.
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Gumenyuk, V.V., Starikova, Z.A., Nekrasov, Y.S. et al. Synthesis and properties of ferrocenylalkyl derivatives of indazole. Russian Chemical Bulletin 51, 1894–1899 (2002). https://doi.org/10.1023/A:1021360704054
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DOI: https://doi.org/10.1023/A:1021360704054